Skip to main content
Log in

An effective approach to reducing fire hazards of rigid polyurethane foam: fire protective coating

  • Brief Communication
  • Published:
Journal of Coatings Technology and Research Aims and scope Submit manuscript

Abstract

The huge surface area of rigid polyurethane foam (RPUF) is the key factor for easy ignition and rapid fire spread when it is exposed to heat sources. The main aim of this work was to fabricate a fire protective coating on the surface of RPUF and investigate the effect of fire protective coating on flame retardancy and combustion properties of RPUF. Waterborne intumescent fireproof coating was prepared and then brushed onto the surface of RPUF. The effect of fire protective coating thickness on flame retardancy and combustion properties of RPUF was evaluated by a cone calorimeter. The heat release rate, total smoke production, and mass loss of the coated RPUF were greatly reduced compared with those of pure RPUF. The results indicated that fire protective coating could enhance the flame retardancy of the RPUF, which may be due to the fire protective coating acting as a good physical barrier to suppress the heat release, combustible gases released during the combustion process.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3

References

  1. Zhang, XY, Wang, GH, Liu, D, Wang, Y, “Applications of Rigid Polyurethane Foam Insulation Materials in Architectural Energy Conservation.” Prog. Renew. Sustain. Energy, 608–609 1783–1785 (2013)

    Google Scholar 

  2. Yang, HY, Wang, X, Song, L, Yu, B, Yuan, Y, Hu, Y, Yuen, RKK, “Aluminum Hypophosphite in Combination with Expandable Graphite as a Novel Flame Retardant System for Rigid Polyurethane Foams.” Polym. Adv. Technol., 25 (9) 1034–1043 (2014)

    Article  Google Scholar 

  3. Yuan, Y, Yang, HY, Yu, B, Shi, YQ, Wang, W, Song, L, Hu, Y, Zhang, YM, “Phosphorus and Nitrogen-Containing Polyols: Synergistic Effect on the Thermal Property and Flame Retardancy of Rigid Polyurethane Foam Composites.” Ind. Eng. Chem. Res., 55 (41) 10813–10822 (2016)

    Article  Google Scholar 

  4. Hu, XM, Wang, DM, “Enhanced Fire Behavior of Rigid Polyurethane Foam by Intumescent Flame Retardants.” J. Appl. Polym. Sci., 129 (1) 238–246 (2013)

    Article  Google Scholar 

  5. Feng, FF, Qian, LJ, “The Flame Retardant Behaviors and Synergistic Effect of Expandable Graphite and Dimethyl Methylphosphonate in Rigid Polyurethane Foams.” Polym. Compos., 35 (2) 301–309 (2014)

    Article  Google Scholar 

  6. Luo, FB, Wu, K, Lu, MG, Nie, SB, Li, XY, Guan, XX, “Thermal Degradation and Flame Retardancy of Microencapsulated Ammonium Polyphosphate in Rigid Polyurethane Foam.” J. Therm. Anal. Calorim., 120 (2) 1327–1335 (2015)

    Article  Google Scholar 

  7. Wang, C, Wu, YC, Li, YC, Shao, Q, Yan, XR, Han, C, Wang, Z, Liu, Z, Guo, ZH, “Flame-Retardant Rigid Polyurethane Foam with a Phosphorus-Nitrogen Single Intumescent Flame Retardant.” Polym. Adv. Technol., 29 (1) 668–676 (2018)

    Article  Google Scholar 

  8. Xu, W, Wang, GJ, Zheng, XR, “Research on Highly Flame-Retardant Rigid PU Foams by Combination of Nanostructured Additives and Phosphorus Flame Retardants.” Polym. Degrad. Stab., 111 142–150 (2015)

    Article  Google Scholar 

  9. Yang, R, Hu, WT, Xu, L, Song, Y, Li, JC, “Synthesis, Mechanical Properties and Fire Behaviors of Rigid Polyurethane Foam with a Reactive Flame Retardant Containing Phosphazene and Phosphate.” Polym. Degrad. Stab., 122 102–109 (2015)

    Article  Google Scholar 

  10. Singh, H, Jain, AK, Sharma, TP, “Effect of Phosphorus-Nitrogen Additives on Fire Retardancy of Rigid Polyurethane Foams.” J. Appl. Polym. Sci., 109 (4) 2718–2728 (2008)

    Article  Google Scholar 

  11. Thirumal, M, Khastgir, D, Nando, GB, Naik, YP, Singha, NK, “Halogen-Free Flame Retardant PUF: Effect of Melamine Compounds on Mechanical, Thermal and Flame Retardant Properties.” Polym. Degrad. Stab., 95 (6) 1138–1145 (2010)

    Article  Google Scholar 

  12. Xing, WY, Yuan, HX, Zhang, P, Yang, HY, Song, L, Hu, Y, “Functionalized Lignin for Halogen-Free Flame Retardant Rigid Polyurethane Foam: Preparation, Thermal Stability, Fire Performance and Mechanical Properties.” J. Polym. Res., 20 (9) 234 (2013)

    Article  Google Scholar 

  13. Zatorski, W, Brzozowski, ZK, Kolbrecki, A, “New Developments in Chemical Modification of Fire-Safe Rigid Polyurethane Foams.” Polym. Degrad. Stab., 93 (11) 2071–2076 (2008)

    Article  Google Scholar 

  14. Modesti, M, Lorenzetti, A, Simioni, F, Camino, G, “Expandable Graphite as an Intumescent Flame Retardant in Polyisocyanurate-Polyurethane Foams.” Polym. Degrad. Stab., 77 (2) 195–202 (2002)

    Article  Google Scholar 

Download references

Acknowledgments

The work was financially supported by the Opening Fund of State Key Laboratory of Coal Mine Disaster Dynamics and Control, Chongqing University (No. 2011DA105287-FW201608), the Opening Fund of large-scale instrument and equipment, Chongqing University (No. 201612150021), the National Natural Science Foundation of China (No. 51603025), the Fundamental Research Funds for the Central Universities, Chongqing University (106112016CDJXY130004, 106112017CDJXY130002).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Hongyu Yang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, H., Yang, H., Chen, M. et al. An effective approach to reducing fire hazards of rigid polyurethane foam: fire protective coating. J Coat Technol Res 16, 257–261 (2019). https://doi.org/10.1007/s11998-018-0149-1

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11998-018-0149-1

Keywords

Navigation