Skip to main content
Log in

Spark plasma sintered AlN-BN composites and its thermal conductivity

  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

A series of samples of hexagonal boron nitride-aluminum nitride ceramic composites with different amounts of CaF2 as sintering aid were prepared by spark plasma sintered at 1700–1850 °C for 5 min. The addition of CaF2 effectively lowered the sintering temperature and promoted the densification of AlN-BN composites. With the increase of sintering temperature, the density increased, and the contiguity of AlN grains enhanced in AlN-BN composites. Thermal conductivity of AlN-BN composites increased with the increase in CaF2 content and sintering temperature, and there is a maximum value of 78.6 W·m−1·K−1 when the sample with 3wt% CaF2 sintered at 1800 °C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M Gonzalez, A Ibarra. The Dielectric Behavior of Commercial Polycrystalline Aluminum Nitride [J]. Diamond and Related Materials, 2000, 9(3–6):467–471

    Article  CAS  Google Scholar 

  2. C A Slack. Nonmetallic Crystals with High Thermal Conductivity[J]. J. Phys. Chem. Solids., 1973, 34(2):321–335

    Article  ADS  CAS  Google Scholar 

  3. L M Sheppard. Aluminum Nitride: A Versatile but Challenging Material[J]. Ceramic Bulletin, 1990, 60(11):1801–1812

    Google Scholar 

  4. Komiyama B, Kiyokawa M, marstui T. Open Resonator for Precision Dielectric Measurements in the 100 GHz Band[J]. IEEE Trans. on Microwave Theory and Techniques, 1991, 39(10):1792–1799

    Article  ADS  Google Scholar 

  5. Mingli Qin, Xuanhui Qu, Bohua Duan, et al. Fabrication of High Density AlN-BN Composite Ceramics by Presureless Sintering[J]. Journal of Inorganic Materials, 2005, 20(1):245–250

    CAS  Google Scholar 

  6. Tiekun Jia, Wei-min Wang. Processing Research of AlN-BN Composites Fabricated by In Situ Reaction[J]. Journal of Wuhan University of Technology, 2006, 28(1):1–3

    Google Scholar 

  7. Guojun Zhang, Jianfeng Yang, Motohide Ando, et al. Reaction Synthesis of Aluminum Nitride-Boron Nitride Composites Based on the Nitridation of Aluminum Boride[J]. J. Am. Ceram. Soc., 2002, 85(12):938–944

    Google Scholar 

  8. Takafumi Kusunose, Tohru Sekino, Bum-Sung Kim, et al. Properties of Hot-Pressed AlN/BN Nanocomposites[J]. Material Science Forum, 2003, 439:131–136

    Article  CAS  Google Scholar 

  9. Shengbo Guo, Weimin Wang. Fabrication of C/BN Laminated Composites by Spark Plasma Sintering[J]. Journal of Wuhan University of Technology, 2006, 28(12):8–10

    Google Scholar 

  10. K A Khor, K H Cheng, L G Yu, et al, Thermal Conductivity and Dielectric Constant of Spark Plasma Sintered Aluminum Nitride[J]. Materials Science and Engineering A, 2003, 347(1–2):303–305

    Google Scholar 

  11. Y Xiong, Z Y Fu, H Wang, et al. Microstructure and IR Transmittance of Spark Plasma Sintering Translucent AlN Ceramics with CaF2 Additive[J]. Materials Science and Engineering B, 2005, 123:57–62

    Article  CAS  Google Scholar 

  12. Peter Greil, Michael Kulig, Dachamir Hotza. Aluminum Nitride Ceramics with High Thermal Conductivity from Gas-Phase Synthesized Powders[J]. J. Eur. Ceram. Soc., 1994, 13(3):229–237

    Article  CAS  Google Scholar 

  13. Liang Qiao, Heping Zhou, Kexin Chen, et al. Effects of Li2O on the Low Temperature Sintering and Thermal Conductivity of AlN Ceramics[J]. J. Eur. Ceram. Soc., 2003, 23(9):1517–1524

    Article  CAS  Google Scholar 

  14. Masahiko Tajika, Hideaki Matsubara, William Rafanicllo, Effect of Grain Contiguity on the Thermal Diffusivity of Aluminum Nitride[J]. J. Am. Ceram. Soc., 1999, 82(6):1573–1575

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Weimin Wang.

Additional information

Funded by New Century Excellent Talents in University of the Ministry of Education of China (No. NCET-04-0722) and Doctoral Fund of Ministry of Education of China (No. 20060497003)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhao, H., Wang, W., Wang, H. et al. Spark plasma sintered AlN-BN composites and its thermal conductivity. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 23, 866–869 (2008). https://doi.org/10.1007/s11595-007-6866-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11595-007-6866-4

Keywords

Navigation