Skip to main content
SpringerLink
Log in

Chemisorption of hydrogen on the missing-row Pt(110)-(1 × 2) surface

  • Published:
Topics in Catalysis Aims and scope Submit manuscript

Chemisorption of hydrogen on the missing-row reconstructed Pt(110)-(1 × 2) surface has been studied by TPD, quantitative LEED, and DFT calculations. An (atypical) chemisorption site on the outermost close-packed rows with an ideal coverage of 0.5 ML (β2-state) is found. Adsorption sites on the (111) microfacets are occupied only at higher coverage (β1-state). After exposures of more than 400 L, the TPD spectra clearly reveal the controversly discussed α-state. In the same coverage range, an intense 1 × 4 superstructure becomes visible at LEED energies around 50 eV. The saturation coverage for chemisorption at T = 120 K is 33% higher than assumed previously.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. Fuchs B. Jenewein S. Penner K. Hayek G. Rupprechter D. Wang R. Schlögl J. Calvino S. Bernal (2005) Appl. Cat. A 294 279 Occurrence Handle10.1016/j.apcata.2005.07.043 Occurrence Handle1:CAS:528:DC%2BD2MXhtVyjtLzI

    Article  CAS  Google Scholar 

  2. C. Lu R.I. Masel (2001) J. Phys. Chem. B 105 9793 Occurrence Handle10.1021/jp011684f Occurrence Handle1:CAS:528:DC%2BD3MXmslOgs7s%3D

    Article  CAS  Google Scholar 

  3. W. Chrzanowski A. Wieckowski (1998) Langmuir 14 1967 Occurrence Handle10.1021/la980184j Occurrence Handle1:CAS:528:DyaK1cXhvVKrt78%3D

    Article  CAS  Google Scholar 

  4. P. Segovia D. Purdie M. Hengsberger Y. Baer (1999) Nature 402 504 Occurrence Handle10.1038/990052 Occurrence Handle1:CAS:528:DyaK1MXotFKnt74%3D

    Article  CAS  Google Scholar 

  5. A. Mugarza A. Mascaraque V. Prez-Dieste V. Repain S. Rousset F.J.G. Abajo Particlede J.E. Ortega (2001) Phys. Rev. Lett. 87 107601/1 Occurrence Handle10.1103/PhysRevLett.87.107601 Occurrence Handle1:CAS:528:DC%2BD3MXmt1ehurg%3D

    Article  CAS  Google Scholar 

  6. N. Nilius T.M. Wallis W. Ho (2002) Science 297 1853 Occurrence Handle10.1126/science.1075242 Occurrence Handle1:CAS:528:DC%2BD38XmvFGgs74%3D

    Article  CAS  Google Scholar 

  7. W. Widdra P. Trischberger J. Henk (1999) Phys. Rev. B 60 R5161 Occurrence Handle10.1103/PhysRevB.60.R5161 Occurrence Handle1:CAS:528:DyaK1MXlt1yis7s%3D

    Article  CAS  Google Scholar 

  8. W. Widdra (2001) Appl. Phys. A 72 395 Occurrence Handle1:CAS:528:DC%2BD3MXis1aluro%3D Occurrence Handle10.1007/s003390100752

    Article  CAS  Google Scholar 

  9. Z. Zhang M. Minca C. Deisl T. Loerting A. Menzel E. Bertel R. Zucca J. Redinger (2004) Phys. Rev. B 70 121401 Occurrence Handle10.1103/PhysRevB.70.121401 Occurrence Handle1:CAS:528:DC%2BD2cXotVKqt7s%3D

    Article  CAS  Google Scholar 

  10. G. Burns (1985) Solid State Physics Academic Press New York

    Google Scholar 

  11. K. Christmann (1988) Surf. Sci. Rep. 9 1 Occurrence Handle10.1016/0167-5729(88)90009-X

    Article  Google Scholar 

  12. J.R. Engstrom W. Tsai W.H. Weinberg (1987) J. Chem. Phys. 87 3104 Occurrence Handle10.1063/1.453048 Occurrence Handle1:CAS:528:DyaL2sXlvVChurs%3D

    Article  CAS  Google Scholar 

  13. C.S. Shern (1992) Surf. Sci. 264 171 Occurrence Handle10.1016/0039-6028(92)90175-6 Occurrence Handle1:CAS:528:DyaK38XhvVWqurY%3D

    Article  CAS  Google Scholar 

  14. W. Stenzel S.A. Jahnke Y. Song H. Conrad (1991) Progress in Surf. Sci. 35 159 Occurrence Handle10.1016/0079-6816(90)90033-G

    Article  Google Scholar 

  15. E. Kirsten G. Parschau W. Stocker K.H. Rieder (1990) Surf. Sci. 231 L183 Occurrence Handle10.1016/0039-6028(90)90190-J Occurrence Handle1:CAS:528:DyaK3cXks1Gqtrw%3D

    Article  CAS  Google Scholar 

  16. G. Kresse J. Hafner (2000) Surf. Sci. 459 287 Occurrence Handle10.1016/S0039-6028(00)00457-X Occurrence Handle1:CAS:528:DC%2BD3cXktlCmt7s%3D

    Article  CAS  Google Scholar 

  17. G. Kresse and J. Furthmüller, Phys. Rev. B 54 (1996) 11169, see also URL: http://cms.mpi.univie.ac.at/vasp; G. Kresse and D. Joubert, Phys. Rev. B 59 (1999) 1758.

  18. Y. Wang J. Perdew (1991) Phys. Rev. B 44 13298 Occurrence Handle10.1103/PhysRevB.44.13298

    Article  Google Scholar 

  19. S. Wilke D. Hennig R. Löber (1994) Phys. Rev. B 50 2548 Occurrence Handle10.1103/PhysRevB.50.2548 Occurrence Handle1:CAS:528:DyaK2cXmtl2js70%3D

    Article  CAS  Google Scholar 

  20. G. Anger H.F. Berger M. Luger A.W.S. Feistritzer K.D. Rendulic (1989) Surf. Sci. 219 L583 Occurrence Handle10.1016/0039-6028(89)90504-9 Occurrence Handle1:CAS:528:DyaL1MXmtVamu7g%3D

    Article  CAS  Google Scholar 

  21. P. Hanesch E. Bertel (1997) Phys. Rev. Lett. 79 1523 Occurrence Handle10.1103/PhysRevLett.79.1523 Occurrence Handle1:CAS:528:DyaK2sXlvVCru7c%3D

    Article  CAS  Google Scholar 

  22. W. Dong V. Ledentu P. Sautet E. Eichler J. Hafner (1998) Surf. Sci. 411 123 Occurrence Handle10.1016/S0039-6028(98)00354-9 Occurrence Handle1:CAS:528:DyaK1cXlvFGnt78%3D

    Article  CAS  Google Scholar 

  23. A. Menzel K. Swamy R. Beer P. Hanesch E. Bertel U. Birkenheuer (2000) Surf. Sci. 454–456 88 Occurrence Handle10.1016/S0039-6028(00)00074-1

    Article  Google Scholar 

  24. E. Bertel N. Memmel G. Rangelov U. Bischler (1993) Chem. Phys. 177 337 Occurrence Handle10.1016/0301-0104(93)80016-3 Occurrence Handle1:CAS:528:DyaK2cXhsF2msw%3D%3D

    Article  CAS  Google Scholar 

  25. R.K. Sharma W.A. Brown D.A. King (1998) Surf. Sci. 414 68 Occurrence Handle10.1016/S0039-6028(98)00467-1 Occurrence Handle1:CAS:528:DyaK1cXmsVOhs7g%3D

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Physical Chemistry, University of Innsbruck, Innsbruck, 6020, Austria

    M. Minca, S. Penner, T. Loerting, A. Menzel & E. Bertel

  2. Center for Computational Materials Science, Vienna University of Technology, Vienna, 1060, Austria

    R. Zucca & J. Redinger

Authors
  1. M. Minca
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. Penner
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. Loerting
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. Menzel
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. Bertel
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. R. Zucca
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. J. Redinger
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. Menzel.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Minca, M., Penner, S., Loerting, T. et al. Chemisorption of hydrogen on the missing-row Pt(110)-(1 × 2) surface. Top Catal 46, 161–167 (2007). https://doi.org/10.1007/s11244-007-0326-4

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11244-007-0326-4

Keywords

Search

Navigation