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Monomeric and polymeric structures derived from 3,3′,4,4′-biphenyltetracarboxylic acid, phenanthroline and metal ions

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Abstract

Under similar hydrothermal synthetic conditions, the reactions of Fe(NO3)3/FeCl2, CuCl2, NiCl2, and CdCl2 with phenanthroline (phen) and 3,3′,4,4′-biphenyltetracarboxylic acid (H4BPTC) afforded complexes [Fe(phen)3](H3BPTC)2 (1), [Cu(phen)(BPTC)0.5 · H2O] · H2O (2), [Ni3(phen)3(BPTC)1.5(H2O)5] · 4H2O (3) and [Cd(phen)(BPTC)0.5] · H2O (4). The short Fe–N distance in the monomeric Fe(phen)3(H3 BPTC)2 (1) shows that the Fe(II) is in a low-spin state. H3 BPTC4− acts as a counter-ion in this complex. In [Cu(phen)(BPTC)0.5 · H2O] · H2O (2), the central Cu(II) is five-coordinated in a square-pyramidal geometry. The ligand BPTC4− is centrosymmetric and the four deprotonated carboxylic groups of BPTC4− are coordinated to four different copper ions to form a 1D ladder complex indicating a comparatively strong coordination. In [Ni3(phen)3(BPTC)1.5(H2O)5] · 4H2O (3), all nickel(II) atoms are in an octahedral coordination environment. There are two different BPTC4− ligands; one is centrosymmetric and the other is asymmetric. Metal ions are linked through fully deprotonated BPTC4− ligands to form a 2D metal-organic sheet. [Cd(phen)(BPTC)0.5] · H2O (4) has a 3D metal-organic framework. TG, IR, and fluorescence data for the complexes are presented.

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Acknowledgment

The project was supported by the Development Foundation of Shanghai Municipal Education Committee, China (Grant No. 06AZ098).

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Authors and Affiliations

  1. Department of Chemistry, Shanghai University, Shanghai, 200444, People’s Republic of China

    Shourong Zhu, Hui Zhang, Yongmei Zhao & Mingxing Li

  2. Instrumental Analysis and Research Center, Shanghai University, Shanghai, 200444, People’s Republic of China

    Min Shao

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  1. Shourong Zhu
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  2. Hui Zhang
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  3. Min Shao
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  4. Yongmei Zhao
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Correspondence to Shourong Zhu.

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Zhu, S., Zhang, H., Shao, M. et al. Monomeric and polymeric structures derived from 3,3′,4,4′-biphenyltetracarboxylic acid, phenanthroline and metal ions. Transition Met Chem 33, 669–680 (2008). https://doi.org/10.1007/s11243-008-9095-6

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  • DOI: https://doi.org/10.1007/s11243-008-9095-6

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