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Two hydrogen-bond-cross-linked molybdenum (VI) network polymers: synthesis, crystal structures and cyclooctene epoxidation with H2O2

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An Erratum to this article was published on 23 September 2009

Abstract

Two molybdenum (VI) hydrogen-bonded network polymers [MoO2F4]·(4,4′-H2bpd)(H2O)2 (1) and [MoO2Cl3(H2O)]·(4,4′-H2bpd)Cl (2) (bpd = bipiperidine) have been synthesized and examined as catalysts for epoxidation of cyclooctene. Complexes of the Mo compounds containing the bpd ligand are prepared and characterized by infrared spectroscopy, thermogravimetric and elemental analyses. They have been structurally characterized by single crystal X-ray diffraction analysis. The structures of both the complexes are shown to be comprised of molybdenum and two protonated N-ligand cations that have resulted in a cross-linked hydrogen-bonded network structure. These complexes are applicable as catalysts for the cis-cyclooctene epoxidation reactions with hydrogen peroxide as a source of oxygen and NaHCO3 as a cocatalyst. It has been observed that the formation of the oxidant peroxymonocarbonate ion, HCO4 − by hydrogen peroxide and bicarbonate enhances the epoxidation reaction. Both the complexes have exhibited a good activity and a very high selectivity for the formation of cyclooctene oxide.

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Acknowledgments

This work was supported by the NSFC (grant no. 50773003) and PetroChina Innovation Foundation (2008D-5006-05-03).

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Authors and Affiliations

  1. School of Materials Science and Engineering, University of Science and Technology Beijing, 100083, Beijing, People’s Republic of China

    Jia Li, Ge Wang & Mu Yang

  2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, 130012, Changchun, People’s Republic of China

    Jia Li & Zhan Shi

  3. Department of Chemistry, Michigan Technological University, Houghton, MI, 49931, USA

    Rudy L. Luck

Authors
  1. Jia Li
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  2. Ge Wang
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  3. Zhan Shi
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  4. Mu Yang
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Corresponding authors

Correspondence to Ge Wang or Zhan Shi.

Additional information

An erratum to this article can be found at http://dx.doi.org/10.1007/s11224-009-9515-z

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Li, J., Wang, G., Shi, Z. et al. Two hydrogen-bond-cross-linked molybdenum (VI) network polymers: synthesis, crystal structures and cyclooctene epoxidation with H2O2 . Struct Chem 20, 869–876 (2009). https://doi.org/10.1007/s11224-009-9485-1

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  • DOI: https://doi.org/10.1007/s11224-009-9485-1

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