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A new mixed ligand coordination polymer of Mn(II): structural aspect and cryomagnetic study

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Abstract

A new 1-D polymeric chain complex [Mn(pydc)(1,10-phen)]n· nH2O (pydc = pyridine-2,3-dicarboxylate, 1,10-phen = 1,10-phenanthroline) has been synthesised and characterised by elemental analysis, FT-IR spectrum, thermal analysis and variable temperature magnetic susceptibility studies. Single crystal X-ray diffraction study reveals that the central Mn(II) ion is in a distorted octahedral coordination geometry, and is coordinated to pydc and 1,10-phen. The complex shows interesting hydrogen bond modes involving the dicarboxylates and lattice water molecules. The presence of weak antiferromagnetic coupling with J = −0.72 cm−1 for the complex has been concluded from the cryomagnetic susceptibility studies.

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Acknowledgements

The work is financially supported by All India Council for Technical Education, Government of India. Joy Chakraborty is especially grateful to the University Grants Commission, New Delhi, Government of India, for awarding a Senior Research Fellowship to him.

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Authors and Affiliations

  1. Department of Chemistry, Jadavpur University, Kolkata, 700 032, West Bengal, India

    Shyamapada Shit, Joy Chakraborty & Samiran Mitra

  2. Department of Chemistry, Durham University, South Road, Durham, DH1 3LE, UK

    Judith A. K. Howard & E. C. Spencer

  3. Institut de Chimie de la Matière Condensée de Bordeaux, UPR CNRS9048-Université de Bordeaux 1, Groupe des Sciences Moléculaires, 87 Av. Doc. A. Schweitzer, F-33608, Pessac, France

    Cédric Desplanches

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  1. Shyamapada Shit
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Correspondence to Samiran Mitra.

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Shit, S., Chakraborty, J., Howard, J.A.K. et al. A new mixed ligand coordination polymer of Mn(II): structural aspect and cryomagnetic study. Struct Chem 19, 553–558 (2008). https://doi.org/10.1007/s11224-008-9324-9

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  • DOI: https://doi.org/10.1007/s11224-008-9324-9

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