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Synthesis and crystal structure of new titanyl phosphate Sr2TiO(PO4)2

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Abstract

New strontium titanyl phosphate Sr2TiO(PO4)2 (1) was synthesized and characterized by X-ray powder diffraction, electron diffraction, high-resolution electron microscopy, and band structure calculations. Titanyl phosphate 1 is isostructural with vanadyl phosphate Sr2VO(PO4)2 and has a layered structure. The titanium atoms are shifted from the centers of the TiO6 octahedra and form short (1.74 Å) titanyl bonds. The structure of 1 is an unusual example of the disordered orientation of the chains formed by TiO6 octahedra in complex titanium phosphates.

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992, Moscow, Russian Federation

    R. V. Shpanchenko, A. A. Tsirlin & E. V. Antipov

  2. Electron Microscopy for Materials Science (EMAT), University of Antwerp, 171 Groenenborgerlaan, 2020, Antwerp, Belgium

    J. Hadermann

Authors
  1. R. V. Shpanchenko
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  2. A. A. Tsirlin
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  3. J. Hadermann
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  4. E. V. Antipov
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Correspondence to R. V. Shpanchenko.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 540–544, March, 2008.

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Shpanchenko, R.V., Tsirlin, A.A., Hadermann, J. et al. Synthesis and crystal structure of new titanyl phosphate Sr2TiO(PO4)2 . Russ Chem Bull 57, 552–556 (2008). https://doi.org/10.1007/s11172-008-0085-9

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  • DOI: https://doi.org/10.1007/s11172-008-0085-9

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