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Hybrid Siloxane-Based Nano Building Blocks for Optical Applications: Optimization of the Synthetic Procedures by Spectroscopic Analysis

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Abstract

Diphenylsilanediol (DPDO) reacts with triethoxysilane (TREOS) in anhydrous conditions and in the presence of pyridine, to form complex mixtures of linear and cyclic condensation products which were identified by 29Si NMR and ATR/FTIR spectroscopies. The distribution of products can be varied by modifying the reaction conditions. Spectroscopic analysis allowed to identify the optimal reagents ratio and concentration for the production of hetero-condensation products minimizing the number of residual –OH groups whose presence would affect the performance of optical waveguides based on the synthesised nano building blocks.

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Authors and Affiliations

  1. Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma Tor Vergata, via della Ricerca Scientifica 1, 00133, Roma, Italy

    M. L. Di Vona

  2. C.I.R.-Centro di Ricerca, Università Campus Bio-Medico, via Longoni 83, 00155, Roma, Italy

    M. Trombetta

  3. Dipartimento di Ingegneria dei Materiali e Tecnologie Industriali, Università di Trento, via Mesiano 77, 38050, Trento, Italy

    S. Dirè & P. Egger

  4. Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma Tor Vergata, via della Ricerca Scientifica 1, 00133, Roma, Italy

    C. D’Ottavi & S. Licoccia

Authors
  1. M. L. Di Vona
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  2. M. Trombetta
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  3. S. Dirè
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  4. P. Egger
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  5. C. D’Ottavi
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  6. S. Licoccia
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Correspondence to M. L. Di Vona.

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Vona, M.L.D., Trombetta, M., Dirè, S. et al. Hybrid Siloxane-Based Nano Building Blocks for Optical Applications: Optimization of the Synthetic Procedures by Spectroscopic Analysis. J Sol-Gel Sci Technol 35, 151–157 (2005). https://doi.org/10.1007/s10971-005-1402-5

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  • DOI: https://doi.org/10.1007/s10971-005-1402-5

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