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Synthesis and crystal structure of tris(ethylenediamine)cobalt(III) bis(tetrachloroaurate(III)) chloride

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Abstract

The binary complex salt [Co(N2C2H8)3][AuCl4]2Cl has been synthesized. Its crystal structure has been determined. Crystal data for C6H24N6Cl9AuCo: a = 20.8976(14) Å, b = 14.4773(9) Å, c = 7.9944(5) Å; β = 110.809(2)°; V = 2260.9(3) Å3, space group C2/c, Z = 4, d calc = 2.798 g/cm3. The plane square environment of the gold atom of the complex anion is completed to a tetragonal pyramid by the chlorine atom of the neighboring complex anion (Au…Cl 3.538 Å). The structure is layered. Layers of complex cations and complex anions alternate along the X axis.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Russia

    E. V. Makotchenko, I. A. Baidina & D. Yu. Naumov

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  1. E. V. Makotchenko
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  2. I. A. Baidina
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  3. D. Yu. Naumov
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Original Russian Text Copyright © 2006 by E. V. Makotchenko, I. A. Baidina, and D. Yu. Naumov

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Translated from Zhurnal Strukturnoi Khimii, Vol. 47, No. 3, pp. 512–516, May–June, 2006.

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Makotchenko, E.V., Baidina, I.A. & Naumov, D.Y. Synthesis and crystal structure of tris(ethylenediamine)cobalt(III) bis(tetrachloroaurate(III)) chloride. J Struct Chem 47, 499–503 (2006). https://doi.org/10.1007/s10947-006-0328-2

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  • DOI: https://doi.org/10.1007/s10947-006-0328-2

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