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The Raman Spectra and Molecular Relaxation Properties of Heterophase Glasses and Melts of K,Ca/CH3COO and Li,K,Cs/CH3COO

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Journal of Applied Spectroscopy Aims and scope

The Raman spectra and conductivity of KCH3COO–Ca(CH3COO)2 and LiCH3COO–KCH3COO–CsCH3COO vitrified acetate systems doped with fine Al2O3 and SiO2 powders at various concentrations were investigated. It was established that at temperatures below the glass formation temperature the addition of fine powders of Al2O3 and SiO2 increases the conductivity of heterophase glasses. It is shown that in the heterogeneous system there are two types of acetate ions differing in relaxation time.

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Authors and Affiliations

  1. Dagestan State University, 43-a M. Gadzhiev Str., Makhachkala, 367000, Russia

    K. Sh. Rabadanov

  2. Dagestan Scientific Center, Russian Academy of Sciences, Analytical Center for Collective Use, Makhachkala, Russia

    K. Sh. Rabadanov, M. M. Gafurov, A. M. Amirov & M. G. Kakagasanov

  3. Kh. I. Amirkhanov Institute of Physics, Dagestan Scientific Center, Russian Academy of Sciences, Makhachkala, Russia

    A. R. Aliev & M. G. Kakagasanov

Authors
  1. K. Sh. Rabadanov
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  2. M. M. Gafurov
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  3. A. R. Aliev
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  4. A. M. Amirov
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  5. M. G. Kakagasanov
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Corresponding author

Correspondence to K. Sh. Rabadanov.

Additional information

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 85, No. 1, pp. 69–75, January–February, 2018.

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Rabadanov, K.S., Gafurov, M.M., Aliev, A.R. et al. The Raman Spectra and Molecular Relaxation Properties of Heterophase Glasses and Melts of K,Ca/CH3COO and Li,K,Cs/CH3COO. J Appl Spectrosc 85, 61–66 (2018). https://doi.org/10.1007/s10812-018-0612-x

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  • DOI: https://doi.org/10.1007/s10812-018-0612-x

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