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New redox deposition-precipitation method for preparation of supported manganese oxide catalysts

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Abstract

A new preparation method has been developed to produce homogeneous coatings of manganese compounds on alumina-coated monoliths by redox deposition-precipitation using acetone as solvent. The deposition is produced by reduction of manganese permanganate with ethanol. The Lewis acid sites on the alumina catalyze this reaction. Thus, the precipitation is produced preferentially on the surface of the monolith and not in the bulk of the solution. Monoliths prepared by this method are very active for the complete oxidation of oxygenated volatile organic compounds (VOCs). These monoliths consist of a mixture of complex phases including aluminum, sulfated alumina, potassium sulfate and manganese oxide.

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References

  1. C. Lahousse A. Bernier P. Grange B. Delmon P. Papaefthimiou T. Ioannides X. Verykios (1998) J. Catal. 178 214 Occurrence Handle10.1006/jcat.1998.2148 Occurrence Handle1:CAS:528:DyaK1cXls1Shtbg%3D

    Article  CAS  Google Scholar 

  2. J.W. Geuss and A.J. Dillen, in: Preparation of Solid Catalysts, G. Ertl, H. Knözinger and J.Weitkamp (eds.), (Weinheim, Wiley-VCH, 1999) pp. 460–460

  3. N. Burgos, M. Paulis and M. Montes, J. Mater. Chem. 13 (2003)

  4. N. Burgos M. Paulis A. Gil L.M. Gandía M. Montes (2000) Stud. Surf. Sci. Catal. 130 593

    Google Scholar 

  5. N. Burgos I. Barrio M. Paulis M. Montes (2002) Actas del XVII Simposio Iberoamericano de Catálisis Porlamar Venezuela 158

    Google Scholar 

  6. L. Hillard T. Lynch D. Lightowlers P. Greenwood (1999) Lab. Autom. Inform. Manage. 34 57 Occurrence Handle10.1016/S1381-141X(99)00004-0

    Article  Google Scholar 

  7. S.J. Gregg K.S.W. Sing (1991) Adsorption, Surface Area and Porosity Academic Press London

    Google Scholar 

  8. (a) K. Wefers, Aluminum (1973) 622.; (b) T-S Yang, T-H. Chang and C-T Yeh, J. Mol. Catal. A 123 (1997) 163

  9. S.G. Lai D. Lee (2002) Tetrahedron 58 9879 Occurrence Handle10.1016/S0040-4020(02)01227-9 Occurrence Handle1:CAS:528:DC%2BD38XovVSlsrs%3D

    Article  CAS  Google Scholar 

  10. J. Luo Q. Zhang A. Huang S.L. Suib (2000) Micropor. Mesopor. Mat. 35–36 209 Occurrence Handle10.1016/S1387-1811(99)00221-8

    Article  Google Scholar 

  11. P.S. Bagus E.S. Ilton J.R. Rustad (2004) Phys. Rev. B 69 205112 Occurrence Handle10.1103/PhysRevB.69.205112

    Article  Google Scholar 

  12. P.S. Bagus R. Broer E.S. Ilton (2004) Chem. Phys. Lett. 394 150 Occurrence Handle10.1016/j.cplett.2004.06.120 Occurrence Handle1:CAS:528:DC%2BD2cXmt1Wmtrw%3D

    Article  CAS  Google Scholar 

  13. V.R. Galakhov M. Demeter S. Bartkowski M. Neumann N.A. Ovechkina E.Z. Kurmaev N.I. Lobachevskaya Ya. M. Mukovskii J. Mitchell D.L. Ederer (2002) Phys. Rev. B 65 113102 Occurrence Handle10.1103/PhysRevB.65.113102

    Article  Google Scholar 

  14. J.A. Odriozola, M.I. Domínguez, M.A. Centeno, I. Barrio, I.␣Legorburu, M. Montes , to be published

  15. F. Kapteijn A.D. Langeveld Particlevan J.A. Moulijn A. Andreïni M.A. Vuurman A.M. Turek J-M. Jheng I.E. Wachs (1994) J. Catal. 150 94 Occurrence Handle10.1006/jcat.1994.1325 Occurrence Handle1:CAS:528:DyaK2cXms1Clu7w%3D

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Grupo de Ingeniería Química, Departamento de Química Aplicada, Facultad de Química de San Sebastián, Universidad del País Vasco, Paseo Manuel de Lardizabal 3, 20018, San Sebastián, Spain

    Izaskun Barrio, Iñigo Legórburu & Mario Montes

  2. Departamento de Química Inorgánica e Instituto de Ciencia de Materiales Sevilla, Centro Mixto CSIC-Universidad de Sevilla, Avda. Américo Vespucio s/n, 41092, Sevilla, Spain

    María Isabel Domínguez, Miguel A’ngel Centeno & José Antonio Odriozola

Authors
  1. Izaskun Barrio
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  2. Iñigo Legórburu
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  3. Mario Montes
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  4. María Isabel Domínguez
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  5. Miguel A’ngel Centeno
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  6. José Antonio Odriozola
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Correspondence to Izaskun Barrio or José Antonio Odriozola.

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Barrio, I., Legórburu, I., Montes, M. et al. New redox deposition-precipitation method for preparation of supported manganese oxide catalysts. Catal Lett 101, 151–157 (2005). https://doi.org/10.1007/s10562-005-4882-6

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  • DOI: https://doi.org/10.1007/s10562-005-4882-6

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