Abstract
The work in this paper is the first report on the green synthesis of the blue light emitter from waxy, flammable solid collected from Cinnamomum camphora by controlled combustion for photonic applications. Analysis with field emission scanning electron microscope and high-resolution transmission electron microscope provides the morphology, whereas the thermogravimetric analysis gives the thermal stability of the soot. The optical and structural characterizations are done by recording UV–Visible, Photoluminescent, and Raman Spectrum. The CIE plot and the power spectrum of the sample show a blue emission at an excitation of 350 nm at room temperature with a quantum yield of 46.15%. The dependence of luminescent behavior on temperature and excitation wavelength reveals that the material is a tunable blue emitter. This green synthesis of the blue light emitter is highly significant, when the world is in search of a simple, phosphor-free, non-toxic, cost-effective material with good quantum efficiency.
Similar content being viewed by others
References
E.F. Schubert, J.K. Kim, Science 308(5726), 1274–1278 (2005)
L.-H. Mao et al., Ind. Eng. Chem. Res 53, 6417–6425 (2014)
A.K.V. Singh, U. Mishra, Scientific Reports 5, 11118 (2015)
X.T. Feng et al., Appl. Phys. Lett 107, 213102 (2015)
G.M. Farinola, R. Ragni, Chem. Soc. Rev 40, 3467–3482 (2011)
The Royal Swedish Academy of Sciences. Efficient blue light-emitting diodes leading to bright and energy-saving white light sources. Kungl. Ventenskaps Akademien. (2014)
C.-Y. Sun et al., Nat. Commun 4, 2717 (2013)
H. Ulla et al., International Conference on Optical Engineering (ICOE), IEEE, (2012)
K. Jiang et al., Angew. Chem. Int. Ed 54, 1–5 (2015)
X. Zhang et al., ACS NANO 7(12), 11234–11241 (2013)
J. Liu et al., J. Mater. Chem. 18(14), 1659–1666 (2008)
R. Ma et al., IMID Dig 8, 60 (2011)
CIE Commission internationale de l’Eclairage proceedings. Cambridge University Press (1932)
S. Thomas, G. John, Trans. Opt. Soc. 33(3), 73–134 (1931–32)
“IEC 61966-2-1:1999"IEC Webstore. International Electrotechnical Commission, Retrieved 3 March 2017
Y.R. Sun et al., Nature 440, 908 (2006)
M.F. Wu et al., Adv. Funct. Mater 17, 1887 (2007)
M.S. Swapna et al., JOJ Material Sci 1(4), 555566 (2017)
J.-Y. Li, et al., Langmuir 33, 1043–1050 (2017)
R.T. Wegh, H. Donker, K.D. Oskam, A. Meijerink, Science 283, 663 (1999)
Q.Y. Zhang, C.H. Yang, Z.H. Jiang, X.H. Ji, Appl. Phys. Lett 90, 061914 (2007)
Operation Manual. http://www.HORIBA.com/scientific
D.-C. Yu, Light: Sci. Appl. 4, e344 (2015)
A.C. Ferrari, Robertson, J. Phys. Rev. B 61, 14095–14107 (2000)
C. Thomsen, C. Reich, Phys. Rev. Lett 85, 5214 (2000)
L.S.K. Pang, J.D. Saxby, S.P. Chatfield, J. Phys. Chem 97, 6941–6942 (1993)
O.M. Dunens, K.J. MacKenzie, A.T. Harris, Environ. Sci. Technol 43, 7889–7894 (2009)
J.H. Lehman, M. Terrones, E. Mansfield, K.E. Hurst, V. Meunier. Carbon 49, 2581 – 2602 (2011)
M. Kumar, Y. Ando, J. Phys.: Conf. Ser. 61, 643–646 (2007)
G. Oza et al., Sci. Rep. 6, 21286
B.N. Sahoo, B. Kandasubramanian, RSC Adv 4, 11331 (2017)
M. Kumar, Y. Ando, Diam. Relat. Mater. 12, 1845–1850 (2003)
T. Uchida et al., Jpn. J. Appl. Phys 45, 8027–8029 (2006)
M.S. Swapna, S. Sankararaman, J Mater Sci Nanotechnol 5(1), 104 (2017)
Z.-H. Wen, X.-B. Yin, RSC Advs 6, 27829–27835 (2016)
N. Anu Mohan, B. Manoj, Int. J. Electrochem. Sci 7, 9537–9549 (2012)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Swapna, M.S., Saritha Devi, H.V. & Sankararaman, S. Camphor soot: a tunable light emitter. Appl. Phys. A 124, 50 (2018). https://doi.org/10.1007/s00339-017-1445-9
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00339-017-1445-9