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PAHs and BTEX in Groundwater of Gasoline Stations from Rio de Janeiro City, Brazil

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Abstract

PAHs and BTEX were studied in groundwater from monitoring wells of gasoline stations of Rio de Janeiro City, Brazil during 2003 and 2004. Total PAH concentration ranged from 0.05 to 84.9 μg/L. Total BTEX concentration varied between not-detected to 3.6 × 103 μg/L. Some samples exceeded the maximum concentration limit of Brazilian regulations for benzene in fresh or drinking water. Carcinogenic PAHs were found in few samples but only one sample in each year exceeded the regulated concentrations for benzo[a]pyrene. The concentrations of PAHs and BTEX indicate that some places may be contaminated by gasoline leakage.

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References

  • ABNT – Associação Brasileira de Normas Técnicas (1997) Construção de poços de monitoramento e de amostragem – NBR 13895, Rio de Janeiro, Brazil

    Google Scholar 

  • ABNT – Associação Brasileira de Normas Técnicas (2000) Posto de serviço – Poço de monitoramento para detecção de vazamento – NBR 14623, Rio de Janeiro, Brazil

    Google Scholar 

  • Brazilian Health Ministry (2004) Portaria MS 518, Brasília, Brazil

    Google Scholar 

  • CONAMA – Brazilian Environment Ministry (1986) Resolução CONAMA 20. Brasília, Brazil

    Google Scholar 

  • CONAMA – Brazilian Environment Ministry (2000) Resolução CONAMA 273. Brasília, Brazil

    Google Scholar 

  • CONAMA – Brazilian Environment Ministry (2005) Resolução CONAMA 357. Brasília, Brazil

    Google Scholar 

  • Corseuil HX, Kaipper BIA, Fernandes M (2004) Cosolvency effect in subsurface systems contaminated with petroleum hydrocarbons and ethanol. Water Res 38:1449–1456

    Article  CAS  Google Scholar 

  • Day MJ, Reinke RF, Thomson JAM (2001) Fate and transport of fuel components below slightly leaking underground storage tanks. Environ Forensics 2:21–28

    CAS  Google Scholar 

  • IARC – International Agency for Research on Cancer (2007) Complete list of agents, mixtures and exposures evaluated and their classification

  • IPCS – International Programme on Chemical Safety (1996a) Diesel fuel and exhaust emissions. World Health Organization, Geneva

    Google Scholar 

  • IPCS – International Programme on Chemical Safety (1996b) Ethylbenzene. World Health Organization, Geneva

    Google Scholar 

  • IPCS – International Programme on Chemical Safety (1997) Xylenes, World Health Organization, Geneva

    Google Scholar 

  • IPCS – International Programme on Chemical Safety (1998) Selected non-heterocyclic polycyclic aromatic hydrocarbons, World Health Organization, Geneva

    Google Scholar 

  • Iturbe R, Flores RM, Torres LG (2003) Subsoil contaminated by hydrocarbons in na out-of-service oil distribution and storage station in Zacatecas, Mexico. Environ Geol 44:608–620

    Article  CAS  Google Scholar 

  • Iturbe R, Flores C, Flores RM, Torres LG (2005) Subsoil TPH and other petroleum fractions-contamination levels in an oil storage and distribution station in north-central Mexico. Chemosphere 61:1618–1631

    Article  CAS  Google Scholar 

  • Kelley CA, Hammer BT, Coffin RB (1997) Concentrations and stable isotope values of BTEX in gasoline-contaminated ground water. Environ Sci Technol 31:2469–2472

    Article  CAS  Google Scholar 

  • Lee LS, Hagwall M, Delfino JJ, Rao PSC (1992) Partioning of polycyclic aromatic hydrocarbons from diesel into water. Environ Sci Technol 26:2104–2110

    Article  CAS  Google Scholar 

  • Menchini E, Bertolaccini MA, Taggi F, Falleni F, Monfredini F (1999) A 3-year study of relationships among atmospheric concentrations of polycyclic aromatic hydrocarbons, carbon monoxide and nitrogen oxides at an urban site. Sci Total Environ 241:27–37

    Article  Google Scholar 

  • Monod A, Sive BC, Avino P, Chen T, Blake DR, Rowland FS (2001) Monoaromatic compounds in ambient air of various cities: a focus on correlations between xylenes and ethylbenzene. Atmos Environ 35:135–149

    Article  CAS  Google Scholar 

  • Odermatt JR (1994) Natural chromatographic separation of benzene, toluene, ethylbenzene and xylenes (BTEX compounds) in a gasoline contaminated ground water aquifer. Org Geochem 21:1141–1150

    Article  CAS  Google Scholar 

  • Pereira Netto AD, Moreira JC, Dias AEXO, Arbilla G, Ferreira LFV, Oliveira AS, Barek J (2000) Avaliação da contaminação humana por hidrocarbonetos policíclicos aromáticos (HPAs) e seus derivados nitrados (NHPAs): uma revisão metodológica. Química Nova 23:765–773

    Article  CAS  Google Scholar 

  • Pereira Netto AD, Sisinno CLS, Moreira JC, Arbilla G, Dufrayer M (2002a) Polycyclic aromatic hydrocarbons in leachate from a municipal solid waste dump of Niterói City, RJ, Brazil. Bull Environ Contam Toxicol 68:148–154

    Article  CAS  Google Scholar 

  • Pereira Netto AD, Muniz FC, Laurentino ECPR (2002b) Identification of polycyclic aromatic hydrocarbons in street dust of Niterói City, RJ, Brazil. Bull Environ Contam Toxicol 68:831–838

    Article  CAS  Google Scholar 

  • Pereira Netto AD, Cunha IF, Muniz FC, Rego ECP (2004) Polycyclic aromatic hydrocarbons in street dust of Niterói City, RJ, Brazil. Bull Environ Contam Toxicol 72:829–835

    Article  CAS  Google Scholar 

  • Powers SE, Hunt CS, Heermann SE, Corseuil HX, Rice D, Alvarez PJJ (2001) The transport and fate of ethanol and BTEX in groundwater contaminated by gashol. Critical Rev Environ Sci Technol 31:79–123

    Article  CAS  Google Scholar 

  • Rosell M, Lacorte S, Ginebreda A, Barceló D (2003) Simultaneous determination of methyl tert-butyl ether and its degradation products, other gasoline oxygenates and benzene, toluene, ethylbenzene and xylenes in Catalonian groundwater by purge-and-trap-gas chromatography-mass spectrometry. J Chromatogr 995:171–184

    Article  CAS  Google Scholar 

  • Tuominen J, Wickström K, Pyysalo H (1986) Determination of polycyclic aromatic compounds by GLC-selected ion monitoring (SIM) technique. J High Res Chromatogr Chromatogr Commun 9:469–471

    Article  CAS  Google Scholar 

  • USEPA – United States Environmental Protection Agency (2003) National primary drinking water standards. <http://www.epa.gov/safewater>

  • Wang Z, Li K, Fingas M, Sigouin L, Menard L (2002) Characterization and source identification of hydrocarbons in water samples using multiple analytical techniques. J Chromatogr A 971:173–184

    Article  CAS  Google Scholar 

  • Zoccolillo L, Babi D, Felli M (2000) Evaluation of polycyclic aromatic hydrocarbons in gasoline by HPLC and GCMS. Chromatographia 52:373–376

    Article  CAS  Google Scholar 

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Acknowledgments

To CNPq, CAPES and FAPERJ for partial financial support.

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Correspondence to Annibal Duarte Pereira Netto.

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do Rego, E.C.P., Pereira Netto, A.D. PAHs and BTEX in Groundwater of Gasoline Stations from Rio de Janeiro City, Brazil. Bull Environ Contam Toxicol 79, 660–664 (2007). https://doi.org/10.1007/s00128-007-9300-x

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  • DOI: https://doi.org/10.1007/s00128-007-9300-x

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