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Scanning tunneling microscopy investigations of corrosive processes on Si(111) surfaces

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Festkörperprobleme 31

Part of the book series: Advances in Solid State Physics ((ASSP,volume 31))

Abstract

Corrosive processes on Si(111) surfaces were systematically studied by scanning tunneling microscopy (STM). These include wet chemical etching of oxide covered Si surfaces in NH4F/HF solutions of varying acidity, the growth of thin oxide layers at room temperatures and atmospheric pressures, both on the (7×7) reconstructed and on the (1×1) hydrogen terminated surface, and corrosive reactions with hydrogen and oxygen, which were studied over a wide temperature range. Detailed results on the atomic scale mechanisms of these processes were derived from STM images resolving atomic structures on the processed surfaces.

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References

  1. Chemical Perspectives of Microelectronic Materials, ed. by M.E. Gross, J.M. Jasinski and J.T. Yates, Jr. (Materials Research Society, Pittsburgh 1989).

    Google Scholar 

  2. W. Kern, J. Electrochem. Soc. 137, 1887 (1990).

    Article  Google Scholar 

  3. J. Lander and J. Morrison, J. Appl. Phys. 33, 2089 (1962).

    Article  ADS  Google Scholar 

  4. J.M. Jasinski, B.S. Meyerson, and B.A. Scott, Ann. Rev. Phys. Chem. 38, 109 (1987).

    Article  ADS  Google Scholar 

  5. P.O. Hahn and M. Henzler, J. Appl. Phys. 52, 4122 (1981).

    Article  ADS  Google Scholar 

  6. R.S. Becker, G.S. Higashi, Y.J. Chabal, and A.J. Becker, Phys. Rev. Lett. 65, 1917 (1990).

    Article  ADS  Google Scholar 

  7. F.J. Grunthaner, P.J. Grunthaner, R.P. Vasquez, B.F. Lewis, J. Maserijan, and A. Madhukar, J. Vac. Sci. Technol. 16, 1443 (1979).

    Article  ADS  Google Scholar 

  8. Ph. Avouris, J. Phys. Chem. 94, 2240 (1990).

    Article  Google Scholar 

  9. R. Houbertz, U. Memmert, and R.J. Behm, Appl. Phys. Lett. 58, 1027 (1991).

    Article  ADS  Google Scholar 

  10. H.E. Hessel, U. Memmert, and R.J. Behm, in: Dünnschichttechnologien '90, ed. by R. Döhl-Oelze (VDI-Verlag, Düsseldorf 1990), p. 412.

    Google Scholar 

  11. H.E. Hessel, A. Feltz, M. Reiter, U. Memmert, and R.J. Behm, subm. for public.

    Google Scholar 

  12. F. Donig, A. Feltz, M. Kulakov, H.E. Hessel, U. Memmert, and R.J. Behm, to be publ.

    Google Scholar 

  13. A. Feltz, H.E. Hessel, U. Memmert, and R.J. Behm, to be publ.

    Google Scholar 

  14. G.S. Higashi, Y.J. Chabal, G.W. Trucks, and K. Raghavachari, Appl. Phys. Lett. 56, 656 (1990).

    Article  ADS  Google Scholar 

  15. E. Kaspar and H. Jorke, in: Chemistry and Physics of Solid Surfaces VII, ed. by R. Vanselow and R. Howe (Springer, Berlin 1988), p. 557.

    Google Scholar 

  16. E. Hartmann, P.O. Hahn, and R.J. Behm, J. Appl. Phys. in press.

    Google Scholar 

  17. H.E. Hessel, U. Memmert, H. Cerva, and R.J. Behm, J. Vac. Sci. Technol. B, in press.

    Google Scholar 

  18. U. Memmert, H.E. Hessel, J. Wiechers, R. Houbertz, A. Feltz, H. Cerva and R.J. Behm, Proc. of the 7th Conference on Microscopy of Semiconducting Materials Oxford 1991, ed. by A.G. Cullis.

    Google Scholar 

  19. M. Grundner and H. Jacob, Appl. Phys. A39, 73 (1986).

    Article  ADS  Google Scholar 

  20. Ph. Avouris and I.-W. Lyo, Surf. Sci. 242, 1 (1991).

    Article  ADS  Google Scholar 

  21. F.M. Leibsle, A. Samsavar, and T.-C. Chiang, Phys. Rev. B38 5780 (1988).

    Article  ADS  Google Scholar 

  22. U. Memmert and M.L. Yu, Surf. Sci. 245, L185 (1991).

    Article  ADS  Google Scholar 

  23. U. Köhler, J.E. Demuth and R.J. Hamers, J. Vac. Sci. Technol. A7, 2860 (1989).

    Article  ADS  Google Scholar 

  24. T.A. Witten and L.M. Sander, Phys. Rev. Lett. 47, 1400 (1981).

    Article  ADS  Google Scholar 

  25. T. Sakurai, Y. Hasegawa, T. Hashizume, I. Kamiya, T. Ide, I. Sumita, H.W. Pickering, and S. Hyodo, J. Vac. Sci. Technol. A8, 259 (1990).

    Article  ADS  Google Scholar 

  26. R.J. Culbertson, L.C. Feldman, and P.J. Silverman, J. Vac. Sci. Technol. 20, 868 (1982).

    Article  ADS  Google Scholar 

  27. G. Schultze and M. Henzler, Surf. Sci. 124, 337 (1983).

    ADS  Google Scholar 

  28. U. Jansson and K.J. Uram, J. Chem. Phys. 91, 7978 (1989).

    Article  ADS  Google Scholar 

  29. H. Froitzheim, U. Köhler and H. Lammering, Surf. Sci. 149, 537 (1985).

    Article  ADS  Google Scholar 

  30. J.J. Boland, Surf. Sci. 244, 1 (1991).

    Article  ADS  Google Scholar 

  31. K. Takayanagi, Y. Tanishiro, S. Takahagi, and M. Takahashi, Surf. Sci. 164, 367 (1985).

    Article  ADS  Google Scholar 

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Ulrich Rössler

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© 1991 Friedr. Vieweg & Sohn Verlagsgesellschaft mbH

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Memmert, U., Behm, R.J. (1991). Scanning tunneling microscopy investigations of corrosive processes on Si(111) surfaces. In: Rössler, U. (eds) Festkörperprobleme 31. Advances in Solid State Physics, vol 31. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0107867

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  • DOI: https://doi.org/10.1007/BFb0107867

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