Skip to main content
Log in

In search of a recyclable sulphur dioxide sponge—a new look at an old system

  • Waste Management
  • Published:
Environmental Monitoring and Assessment Aims and scope Submit manuscript

Abstract

The sulphur dioxide content and thermal stability of the quinol-SO2 clathrate have been studied by thermogravimetric analysis (TG), its derivative (DTG) and differential scanning calorimetry (DSC). These analyses demonstrated the thermal recoverability of the quinol from the clathrate and hence its potential use as a sponge for SO2 present in the environment as a pollutant. Similarly, Bu4N+I- was found to occlude NO2 and SO2 at 50°C in solution.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Palin, D. E. and Powell, H. M.: 1947, ‘The Structure of Molecular Compounds. Part III. Crystal Structure of Addition Complexes of Quinol with Certain Volatile Compounds’, J. Chem. Soc., 208–221.

  2. Powell, H. M.: 1948, ‘The Structure of Molecular Compounds. Part IV. Clathrate Compounds’, J. Chem. Soc., 61–73.

  3. Palin, D. E. and Powell, H. M.: 1948, ‘The Structure of Molecular Compounds. Part VI. The β-type Clathrate Compounds of Quinol’, J. Chem. Soc., 815–821.

  4. Saltzman, B. E.: 1954, ‘Colorimetric Microdetermination of Nitrogen Dioxide in the Atmosphere’, Anal. Chem., 26, 1949–1955.

    Google Scholar 

  5. Mingos, D. M. P.: 1978, ‘Sulphur Dioxide Complexes of the Transition Metals’, Transition Met. Chem., 3, 1–15.

    Google Scholar 

  6. Davies, J. E. D., Kemula, W., Powell, H. M. and Smith, N. O.: 1983, ‘Inclusion Compounds—Past, Present, and Future’, J. Incl. Phenom., 1, 3–44.

    Google Scholar 

  7. Parsonage, N. G. and Staveley, L. A. K. in Atwood, J. L., Davies, J. E. D. and MacNicol, D. D. (Eds.): 1984, ‘Thermodynamic Studies of Clathrates and Inclusion Compounds’, Inclusion Compounds, Physical Properties and Applications, Vol. 3, Ch. 1, pp. 1–36, and references therein.

  8. Kubas, G. J., Wasserman, H. J. and Ryan, R. R.: 1985, ‘New Metal-Sulfur Complexes from Sulfur Dioxide Reduction by (η 5-C5R5)W(CO)3H (R = H, Me): Structures of [CpW(CO)3]2(μ-S) and [Cp*W(CO)2(μ-S·SO2)]2, a Complex with Strong SO2-Sulfide Bonding’, Organometallics, 4, 419–421.

    Google Scholar 

  9. Kubat-Martin, K. A., Kubas, G. J. and Ryan, R. R.: 1988: ‘Reaction of Sulfur Dioxide with (η 5-C5Me5)Ru(CO)2H: Insertion of SO2 into the Ru-H and Oxygen transfer to Form (η 5-C5Me3)Ru(CO)2SO3H’, Organometallics, 7, 1657–1659.

    Google Scholar 

  10. Chang, S. G. and Liu, D. K.: 1990, ‘Removal of Nitrogen and Sulfur Oxides from Waste Gas Using a Phosphorus/Alkali Emulsion’, Nature, 343, 151–152.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hor, T.S.A., Lee, HK., Leong, YP. et al. In search of a recyclable sulphur dioxide sponge—a new look at an old system. Environ Monit Assess 19, 151–155 (1991). https://doi.org/10.1007/BF00401307

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00401307

Keywords

Navigation