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Fe–H Complexes in Catalysis

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Iron Catalysis

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 33))

Abstract

Organic syntheses catalyzed by iron complexes have attracted considerable attention because iron is an abundant, inexpensive, and environmentally benign metal. It has been documented that various iron hydride complexes play important roles in catalytic cycles such as hydrogenation, hydrosilylation, hydroboration, hydrogen generation, and element–element bond formation. This chapter summarizes the recent developments, mainly from 2000 to 2009, of iron catalysts involving hydride ligand(s) and the role of Fe–H species in catalytic cycles.

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Acknowledgment

We would like to show our respect for the great efforts of all authors, whose names were listed in the references. We wish to thank Dr. Yuji Suzaki for the reference collection.

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Authors and Affiliations

  1. Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka, 558-8585, Japan

    Hiroshi Nakazawa & Masumi Itazaki

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  1. Hiroshi Nakazawa
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  2. Masumi Itazaki
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Correspondence to Hiroshi Nakazawa .

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  1. Universität Stuttgart, Institut für Organische Chemie, Pfaffenwaldring 55, Stuttgart, 70569, Germany

    Bernd Plietker

Appendix

Appendix

The isolated iron hydride complexes introduced in this chapter are listed in Table 12, where the hydride chemical shifts in the 1HNMR spectra and the Fe–H bond distances are summarized.

Table 12  
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Nakazawa, H., Itazaki, M. (2011). Fe–H Complexes in Catalysis. In: Plietker, B. (eds) Iron Catalysis. Topics in Organometallic Chemistry, vol 33. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-14670-1_2

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