Abstract
In 1834 Faraday (1) recorded an interesting phenomenon. In his words: “I formerly described a substance, sulphuret of silver, whose conducting power was increased by heat; and I have since then met with another as strongly affected in the same way: this is fluoride of lead. When a piece of that substance, which had been fused and cooled, was introduced into the circuit of a voltaic battery, it stopped the current. Being heated, it acquired conducting powers before it was visibly red hot in daylight; and even sparks could be taken against it whilst still solid.”
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
M. Faraday, Experimental Researches in Electricity, Art. 1339, Taylor and Francis, London (1839).
M. O’Keeffe and B.G. Hyde, Phil. Mag. 33, 219 (1976).
H. Wiedersich and S. Geller, in The Chemistry of Extended Defects in Nonmetallic Crystals ( L. Eyring and M. O’Keeffe, ed.) North Holland, Amsterdam (1970).
4.T. Takahashi, J. Appl. Electrochem. 3, 79 (1973).
A Kvist and A. Lunden, Z. Naturforschg. 21a, 1509 (1966).
H.-H. Möbius, Z. Chem. 21 100 (1962).
A.R. West, J. Appl. Electrochem. 3, 327 (1973).
C.E. Derrington, A. Lindner and M. O’Keeffe, J. Solid State Chem. 15, 171 (1975).
C.E. Derrington and M. O’Keeffe, Nature Phys. Sci. 246, 44 (1973).
L.E. Nagel and M. O’Keeffe in Fast Ion Transport in Solids ( W. van Gool, ed.) North Holland, Amsterdam (1973).
J.B. Goodenough, H.V.-P. Hong and J.A. Kafalas, Mater. Res. Bull. 11, 203 (1976).
M. O’Keeffe, unpublished data.
D.K. Paul and I.F. Chang, J. Electronic Mater. 3, 709 (1974).
M. O’Keeffe and B.G. Hyde, Acta Cryst. in press.
W.V.. Johnston, H. Wiedersich and G.W. Lindberg, J. Chem. Phys. 51, 3739 (1969).
W.J. Pardee and G.D. Mahan, J. Solid State Chem. 15, 310
L.F, Vereshchagin, S.S. Kabalkina and A.A. Kotilevets, Sov. Phys. JETP 22, 1181 (1966); S.S. Kabalkina, L.F. Vereshchagin and L.M. Lityagina, Sov. Phys. Doklady 12, 946 (1968); Sov. Phys. JETP 29, 803 (1969).
N. Kawai, O. Mishima, M. Togaya and B. leNiendre, Proc. Japan Acad. 51, 627 (1975); L.V. Vereshchagin, E.N. Yakolev and Yu.A. Timofeev, JETP Lett. 21, 304 (1975).
B. A Huberman, Phys. Rev. Lett. 32j 1000 (1974).
P.A. Egelstaff, An Introduction to the Liquid State/ Academic Press, New York (1967).
B.A, Huberman and P.N. Sen, Phys. Rev. Lett. 33, 1379 (1974).
P. Bruesch, S. Strässler and H.R. Zeller, Phys. Stat. Sol. 31, 217 (1975).
C.A. Croxton, Liquid State Physics, Cambridge University Press (1974).
K. Funke and A. Jost, Ber. Bunsen-Gesell. phys. Chem. 75, 436 (1971).
P.A, Egelstaff, Adv. Phys. 11, 203 (1962).
C. Clemen and K. Funke, Ber. Bunsen-Gesell. phys. Chem. 79, 1119 (1975).
C.E. Derrington, A. Navrotsky and M. O’Keeffe, Solid State Comm. IS, 47 (1976).
M. O’Keeffe, to be published.
M. Shand, R.C. Hanson, C.E. Derrington and M. O’`Keeffe, Solid State Comm. 769 (1976).
R.T, Harley, W. Hayes, A.J. Rushworth and J.F. Ryan, J. Phys. C 8, L530 (1975).
R. C, Hanson, T.A, Fjeldly and H.D. Hochheimer, Phys. Stat. Sol. (b) 70, 567 (1975).
J.B. Boyce, to be published.
M.J. Rice and W.L. Roth, J. Solid State Chem. 294 (1972) 114
T.S. Ree, T. Ree and H. Eyring, Proc. Natl. Acad. Sci. (U.S.) 48, 501 (1962).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1976 Plenum Press, New York
About this chapter
Cite this chapter
O’Keeffe, M. (1976). Phase Transitions and Translational Freedom in Solid Electrolytes. In: Mahan, G.D., Roth, W.L. (eds) Superionic Conductors. Physics of Solids and Liquids. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-8789-7_9
Download citation
DOI: https://doi.org/10.1007/978-1-4615-8789-7_9
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4615-8791-0
Online ISBN: 978-1-4615-8789-7
eBook Packages: Springer Book Archive