Elsevier

Microchemical Journal

Volume 59, Issue 2, June 1998, Pages 228-238
Microchemical Journal

Regular Article
Determination of Polyaromatic Hydrocarbons in Atmospheric Particulate Samples by HPLC with Fluorescence Detection: A Field Application

https://doi.org/10.1006/mchj.1998.1611Get rights and content

Abstract

The content of polycyclic aromatic hydrocarbons (PAHs) was monitored in atmospheric particulate matter collected at two highway toll stations in Italy during both winter- and summertime. In particular, the highest concentrations of both total PAHs (28.1 ng/m3) and benzo[a]pyrene (BaP) (5.0 ng/m3) were found outside the cabin at the Viareggio sampling station during wintertime; the lowest concentrations, 2.0 and 0.2 ng/m3, respectively, were observed outside the cabins during summertime, without significant differences between the two sampling stations. The profile of PAH distribution was the same for the samples collected in winter and summer, and the total PAH and BaP concentrations of each sample reflected the traffic load at the two toll stations. This may mean that the presence of PAHs in the areas studied is due mainly to emissions from motor vehicles.

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    PAHs have attracted much attention because of their carcinogenic potential and, consequently, have been included in the list of priority pollutants. Thus, their environmental monitoring is of prime importance [32]. For the separation of PAHs HPLC is one of most used techniques, usually coupled with fluorescence detectors [33,34].

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This article is part of a special section devoted to the Eighth Hungarian–Italian Symposium on Spectrochemistry.

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To whom correspondence should be addressed. Dipartimento di Chimica e Chimica Industriale, Via Risorgimento 35, 56126 Pisa, Italy.

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