Thiosalicylic Acid-Functionalized Silver Nanoparticles Synthesized in One-Phase System

doi:10.1006/jcis.2001.8166

Journal of Colloid and Interface Science

Volume 249, Issue 2, 15 May 2002, Pages 336-345

https://doi.org/10.1006/jcis.2001.8166 Get rights and content

Abstract

A series of silver colloidal dispersions were prepared by two protocols, i.e., addition of the reductant-NaBH₄ and the stabilizer-thiosalicylic acid (TSA) into Ag⁺ solution simultaneously or successively. The products were compared and characterized by TEM, electrochemical measurements, XPS, UV-vis, and FT-IR spectra. The size distributions of the Ag nanoparticles prepared by the former and latter protocols are bimodal and monodisperse, respectively. The analytic results of UV-vis spectra coincide with the TEM observation. A tentative explanation was given to the relationship between particle sizes and different synthetic protocols. The changes of the reduction potential of the reductant invoked a variance in particle diameter and size distribution. Electrochemical measurements corroborated our assumption. The composition information of TSA-derived silver nanoparticles was obtained from XPS and FT-IR spectroscopic measurements.

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Fine Particles and Colloidal DispersionsThiosalicylic Acid-Functionalized Silver Nanoparticles Synthesized in One-Phase System

Abstract

J. Radiat. Phys. Chem.

J. Colloid Interface Sci.

Clusters and Colloids: From Theory to Applications

Clusters of Atoms and Molecules

The Quantum Dot: A Journey into the Future of Microelectronics

Colloidal Gold: Principles, Methods, and Applications

Chem. Rev.

Catal. Rev.-Sci. Eng.

J. Phys. Chem.

J. Phys. Chem.

J. Am. Chem. Soc.

J. Phys. Chem.

Langmuir

J. Phys. Chem. B

J. Phys. Chem.

Langmuir

J. Phys. Chem.

Fine Particles and Colloidal Dispersions
Thiosalicylic Acid-Functionalized Silver Nanoparticles Synthesized in One-Phase System