Limiting partial molar volumes of tetra-n-alkylammonium perchlorates inN,N- dimethylacetamide, triethylphosphate and dimethyl sulfoxide atT =  298.15 K

doi:10.1006/jcht.2000.0725

The Journal of Chemical Thermodynamics

Volume 33, Issue 1, January 2001, Pages 121-133

https://doi.org/10.1006/jcht.2000.0725 Get rights and content

Abstract

The densities of tetraalkylammonium perchlorates R₄NClO₄(R = methyl, or ethyl, or propyl, or butyl) and ammonium perchlorate solutions in N, N - dimethylacetamide, dimethyl sulfoxide, and triethylphosphate have been measured over the whole composition range atT = 298.15 K. From these densities, apparent and limiting partial molar volumes of the electrolytes and ions have been evaluated and used to obtain the partial molar volume for theClO₄⁻ anion.

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Regular ArticleLimiting partial molar volumes of tetra-n-alkylammonium perchlorates inN,N- dimethylacetamide, triethylphosphate and dimethyl sulfoxide atT = 298.15 K

Abstract

J. Chem. Thermodynamics

J. Solution Chem.

J. Solution Chem.

J. Chem. Soc., Faraday Trans. 1

J. Chem. Eng. Data

J. Chem. Soc.

Regular Article
Limiting partial molar volumes of tetra-n-alkylammonium perchlorates inN,N- dimethylacetamide, triethylphosphate and dimethyl sulfoxide atT = 298.15 K