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Uranium(VI) adsorption on surfactant modified heulandite/clinoptilolite rich tuff

Matijašević Srđan (Institut za tehnologiju nuklearnih i drugih mineralnih sirovina, Beograd)
Daković Aleksandra (Institut za tehnologiju nuklearnih i drugih mineralnih sirovina, Beograd)
Tomašević-Čanović Magdalena (Institut za tehnologiju nuklearnih i drugih mineralnih sirovina, Beograd)
Stojanović Mirjana (Institut za tehnologiju nuklearnih i drugih mineralnih sirovina, Beograd)
Ileš Deana (Institut za tehnologiju nuklearnih i drugih mineralnih sirovina, Beograd)

The adsorption of uranium(VI) on heulandite/clinoptilolite rich zeolitic tuff modified with different amounts (2, 5 and 10 meq/100 g) of hexadecyltrimethyl ammonium (HDTMA) ion was investigated. The organozeolites were prepared by ion exchange of inorganic cations at the zeolite surface with HDTMA ions, and the three prepared samples were denoted as OA-2, OA-5 and OA-10. The maximal amount of HDTMAin the organozeolite OA-10 (10 meq/100 g) was equal to the external cation exchange capacity of the starting material. The results showed that uranium( VI) adsorption on unmodified zeolitic tuff was low (0.34 mg uranium(VI)/g adsorbent), while for the organozeolites, the adsorption increased with increasing amount of HDTMA at the zeolitic surface. The highest adsorption indexes were achieved for the organozeolite OA-10, in which all the surface inorganic cations had been replaced with HDTMA. An investigation of the adsorption of uranium(VI) ions onto organozeolite OA-10 at different pH values (3, 6 and 8) showed that the adsorption index increased with increasing amount of adsorbent in the suspension. Since uranium(VI) speciation is highly dependent on pH, from the adsorption isotherms, it can be seen that uranium(VI) adsorption on organozeolite OA-10 at pH 6 and 8 is well described by a Langmuir type of isotherm, while at pH 3, it corresponds to a Type III isotherm. .

Keywords: zeolite, clinoptilolite/heulandite, organozeolite, uranium(VI), adsorption