##############################################################################
#                                                                            #
# This CIF contains the data for a data article accepted for                 #
# publication in IUCrData. It conforms to the requirements of                #
# Notes for Authors for IUCrData, and has been                               #
# peer reviewed under the auspices of IUCrData.                              #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the data    # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_I
_audit_creation_method     'SHELXL-2014/7'
_database_code_depnum_ccdc_archive     'CCDC 1445626'
_chemical_name_systematic
;
(η²,η²-Cycloocta-1,5-diene)(η⁵-indenyl)cobalt(I)
;
_chemical_name_common     ?
_chemical_formula_moiety     'C17 H19 Co'
_chemical_formula_sum     'C17 H19 Co'
_chemical_formula_iupac     '[Co (C8 H12) (C9 H7)]'
_chemical_formula_weight     282.25
_chemical_melting_point     ?
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system     monoclinic
_space_group_name_H-M_alt     'P 21/n'
_space_group_name_Hall     '-P 2yn'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x+1/2, y+1/2, -z+1/2'
    '-x, -y, -z'
    'x-1/2, -y-1/2, z-1/2'
_cell_length_a     8.0307(2)
_cell_length_b     14.4939(3)
_cell_length_c     22.2528(6)
_cell_angle_alpha     90
_cell_angle_beta     98.814(2)
_cell_angle_gamma     90
_cell_volume     2559.55(11)
_cell_formula_units_Z     8
_cell_measurement_reflns_used     3014
_cell_measurement_theta_min     1.62
_cell_measurement_theta_max     27.11
_cell_measurement_temperature     150(2)
_exptl_crystal_description     prism
_exptl_crystal_colour     'red-brown'
_exptl_crystal_size_max     0.35
_exptl_crystal_size_mid     0.34
_exptl_crystal_size_min     0.27
_exptl_crystal_density_diffrn     1.465
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     ?
_exptl_crystal_F_000     1184
_exptl_absorpt_coefficient_mu     1.318
_exptl_absorpt_correction_type     none
_exptl_absorpt_process_details     ?
_exptl_absorpt_correction_T_min     ?
_exptl_absorpt_correction_T_max     ?
_diffrn_ambient_temperature     150(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Stoe IPDS II'
_diffrn_measurement_method     'ω-scans'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     35986
_diffrn_reflns_av_R_equivalents     0.0318
_diffrn_reflns_theta_min     1.683
_diffrn_reflns_theta_max     25.997
_diffrn_reflns_theta_full     25.242
_diffrn_measured_fraction_theta_max     0.999
_diffrn_measured_fraction_theta_full     0.999
_diffrn_reflns_limit_h_min     -9
_diffrn_reflns_limit_h_max     9
_diffrn_reflns_limit_k_min     -17
_diffrn_reflns_limit_k_max     17
_diffrn_reflns_limit_l_min     -27
_diffrn_reflns_limit_l_max     27
_refine_special_details     ?
_reflns_number_total     5024
_reflns_number_gt     4307
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0265
_refine_ls_R_factor_gt     0.0221
_refine_ls_wR_factor_gt     0.0593
_refine_ls_wR_factor_ref     0.0603
_refine_ls_goodness_of_fit_ref     1.028
_refine_ls_restrained_S_all     1.028
_refine_ls_number_reflns     5024
_refine_ls_number_parameters     357
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     mixed
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
                      'w=1/[σ²(Fo²)+(0.0431P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary     ?
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.359
_refine_diff_density_min     -0.386
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Co' 'Co' 0.3494 0.9721
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection
;
X-AREA (Stoe & Cie, 2005)
;
_computing_cell_refinement
;
X-AREA (Stoe & Cie, 2005)
;
_computing_data_reduction
;
X-AREA (Stoe & Cie, 2005)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_molecular_graphics
;
XP in SHELXTL (Sheldrick, 2008) and Mercury (Macrae et al.,
2006)
;
_computing_publication_material
;
publCIF (Westrip, 2010)
;
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Co Co1 0.59531(2) -0.00072(2) 0.23597(2) 0.02402(7) Uani d 1 . .
    C C1 0.84516(16) 0.06045(10) 0.24041(7) 0.0262(3) Uani d 1 . .
    C C2 0.78946(18) 0.01032(10) 0.18505(7) 0.0294(3) Uani d 1 . .
    H H2 0.7702 0.0359 0.1453 0.035 Uiso calc 1 . .
    C C3 0.76847(18) -0.08314(10) 0.19994(7) 0.0318(3) Uani d 1 . .
    H H3 0.7427 -0.1324 0.1719 0.038 Uiso calc 1 . .
    C C4 0.79252(18) -0.09065(10) 0.26417(7) 0.0300(3) Uani d 1 . .
    H H4 0.7762 -0.1448 0.2866 0.036 Uiso calc 1 . .
    C C5 0.84612(18) -0.00198(9) 0.28988(7) 0.0270(3) Uani d 1 . .
    C C6 0.88758(18) 0.03005(11) 0.35024(7) 0.0320(3) Uani d 1 . .
    H H6 0.8853 -0.0106 0.3836 0.038 Uiso calc 1 . .
    C C7 0.93101(19) 0.12060(11) 0.35988(7) 0.0351(3) Uani d 1 . .
    H H7 0.9605 0.1425 0.4004 0.042 Uiso calc 1 . .
    C C8 0.93288(19) 0.18232(11) 0.31084(8) 0.0344(3) Uani d 1 . .
    H H8 0.9652 0.2447 0.3190 0.041 Uiso calc 1 . .
    C C9 0.88928(18) 0.15423(10) 0.25217(7) 0.0310(3) Uani d 1 . .
    H H9 0.8884 0.1967 0.2196 0.037 Uiso calc 1 . .
    C C10 0.47123(19) 0.11738(10) 0.21129(7) 0.0316(3) Uani d 1 . .
    H H10 0.547(2) 0.1588(12) 0.1943(8) 0.039(5) Uiso d 1 . .
    C C11 0.40445(19) 0.04573(10) 0.17247(7) 0.0311(3) Uani d 1 . .
    H H11 0.444(2) 0.0405(11) 0.1338(8) 0.030(4) Uiso d 1 . .
    C C12 0.2365(2) 0.00024(11) 0.17674(8) 0.0363(4) Uani d 1 . .
    H H12A 0.1815 -0.0179 0.1356 0.044 Uiso calc 1 . .
    H H12B 0.1620 0.0450 0.1932 0.044 Uiso calc 1 . .
    C C13 0.25913(19) -0.08530(11) 0.21783(8) 0.0362(4) Uani d 1 . .
    H H13A 0.1589 -0.0924 0.2384 0.043 Uiso calc 1 . .
    H H13B 0.2671 -0.1408 0.1924 0.043 Uiso calc 1 . .
    C C14 0.41473(18) -0.07912(11) 0.26525(7) 0.0316(3) Uani d 1 . .
    H H14 0.463(2) -0.1390(12) 0.2795(8) 0.035(4) Uiso d 1 . .
    C C15 0.45397(19) -0.00372(10) 0.30418(7) 0.0305(3) Uani d 1 . .
    H H15 0.526(2) -0.0130(10) 0.3411(8) 0.031(4) Uiso d 1 . .
    C C16 0.3418(2) 0.08051(11) 0.30450(8) 0.0377(4) Uani d 1 . .
    H H16A 0.3503 0.1045 0.3465 0.045 Uiso calc 1 . .
    H H16B 0.2231 0.0626 0.2907 0.045 Uiso calc 1 . .
    C C17 0.3921(2) 0.15631(11) 0.26299(8) 0.0387(4) Uani d 1 . .
    H H17A 0.2909 0.1924 0.2463 0.046 Uiso calc 1 . .
    H H17B 0.4729 0.1987 0.2872 0.046 Uiso calc 1 . .
    Co Co2 0.03476(2) 0.78868(2) 1.00510(2) 0.02282(6) Uani d 1 . .
    C C18 -0.22601(17) 0.76375(10) 0.96523(7) 0.0275(3) Uani d 1 . .
    C C19 -0.19275(18) 0.85687(10) 0.98738(7) 0.0312(3) Uani d 1 . .
    H H19 -0.2044 0.9113 0.9633 0.037 Uiso calc 1 . .
    C C20 -0.14008(19) 0.85315(11) 1.05075(7) 0.0325(3) Uani d 1 . .
    H H20 -0.1194 0.9047 1.0772 0.039 Uiso calc 1 . .
    C C21 -0.12338(19) 0.75916(11) 1.06809(7) 0.0313(3) Uani d 1 . .
    H H21 -0.0803 0.7369 1.1076 0.038 Uiso calc 1 . .
    C C22 -0.18288(17) 0.70295(10) 1.01557(7) 0.0279(3) Uani d 1 . .
    C C23 -0.19716(19) 0.60644(10) 1.00634(8) 0.0346(3) Uani d 1 . .
    H H23 -0.1673 0.5649 1.0392 0.041 Uiso calc 1 . .
    C C24 -0.2546(2) 0.57421(11) 0.94931(8) 0.0384(4) Uani d 1 . .
    H H24 -0.2671 0.5096 0.9430 0.046 Uiso calc 1 . .
    C C25 -0.29577(19) 0.63447(11) 0.89959(8) 0.0373(4) Uani d 1 . .
    H H25 -0.3344 0.6096 0.8604 0.045 Uiso calc 1 . .
    C C26 -0.28128(19) 0.72780(11) 0.90658(7) 0.0329(3) Uani d 1 . .
    H H26 -0.3078 0.7678 0.8726 0.040 Uiso calc 1 . .
    C C27 0.1724(2) 0.87766(11) 0.96298(8) 0.0365(4) Uani d 1 . .
    H H27 0.108(2) 0.9323(13) 0.9565(9) 0.048(5) Uiso d 1 . .
    C C28 0.1180(2) 0.80406(12) 0.92464(8) 0.0365(4) Uani d 1 . .
    H H28 0.026(3) 0.8137(13) 0.8947(9) 0.050(5) Uiso d 1 . .
    C C29 0.2226(2) 0.72263(13) 0.91177(8) 0.0458(4) Uani d 1 . .
    H H29A 0.3078 0.7431 0.8868 0.055 Uiso calc 1 . .
    H H29B 0.1491 0.6767 0.8878 0.055 Uiso calc 1 . .
    C C30 0.3114(2) 0.67713(12) 0.96903(8) 0.0415(4) Uani d 1 . .
    H H30A 0.4269 0.7024 0.9789 0.050 Uiso calc 1 . .
    H H30B 0.3206 0.6100 0.9619 0.050 Uiso calc 1 . .
    C C31 0.21792(19) 0.69281(11) 1.02245(7) 0.0310(3) Uani d 1 . .
    H H31 0.166(2) 0.6412(12) 1.0364(8) 0.037(5) Uiso d 1 . .
    C C32 0.25222(19) 0.76667(11) 1.06207(7) 0.0329(3) Uani d 1 . .
    H H32 0.226(2) 0.7578(11) 1.1021(8) 0.037(5) Uiso d 1 . .
    C C33 0.3829(2) 0.83998(13) 1.05601(9) 0.0458(4) Uani d 1 . .
    H H33A 0.4962 0.8113 1.0622 0.055 Uiso calc 1 . .
    H H33B 0.3806 0.8870 1.0882 0.055 Uiso calc 1 . .
    C C34 0.3530(2) 0.88699(12) 0.99418(10) 0.0466(4) Uani d 1 . .
    H H34A 0.3814 0.9533 0.9994 0.056 Uiso calc 1 . .
    H H34B 0.4290 0.8596 0.9679 0.056 Uiso calc 1 . .
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Co1 C10 . 2.0142(14) ?
    Co1 C14 . 2.0269(14) ?
    Co1 C15 . 2.0304(15) ?
    Co1 C11 . 2.0336(15) ?
    Co1 C2 . 2.0693(14) ?
    Co1 C4 . 2.0727(14) ?
    Co1 C3 . 2.0844(14) ?
    Co1 C5 . 2.1808(15) ?
    Co1 C1 . 2.1820(13) ?
    C1 C9 . 1.419(2) ?
    C1 C5 . 1.424(2) ?
    C1 C2 . 1.441(2) ?
    C2 C3 . 1.411(2) ?
    C2 H2 . 0.9500 ?
    C3 C4 . 1.417(2) ?
    C3 H3 . 0.9500 ?
    C4 C5 . 1.445(2) ?
    C4 H4 . 0.9500 ?
    C5 C6 . 1.412(2) ?
    C6 C7 . 1.366(2) ?
    C6 H6 . 0.9500 ?
    C7 C8 . 1.413(2) ?
    C7 H7 . 0.9500 ?
    C8 C9 . 1.361(2) ?
    C8 H8 . 0.9500 ?
    C9 H9 . 0.9500 ?
    C10 C11 . 1.404(2) ?
    C10 C17 . 1.506(2) ?
    C10 H10 . 0.974(18) ?
    C11 C12 . 1.518(2) ?
    C11 H11 . 0.964(17) ?
    C12 C13 . 1.535(2) ?
    C12 H12A . 0.9900 ?
    C12 H12B . 0.9900 ?
    C13 C14 . 1.510(2) ?
    C13 H13A . 0.9900 ?
    C13 H13B . 0.9900 ?
    C14 C15 . 1.400(2) ?
    C14 H14 . 0.984(17) ?
    C15 C16 . 1.518(2) ?
    C15 H15 . 0.939(18) ?
    C16 C17 . 1.529(2) ?
    C16 H16A . 0.9900 ?
    C16 H16B . 0.9900 ?
    C17 H17A . 0.9900 ?
    C17 H17B . 0.9900 ?
    Co2 C28 . 2.0169(16) ?
    Co2 C31 . 2.0173(15) ?
    Co2 C32 . 2.0199(16) ?
    Co2 C27 . 2.0200(15) ?
    Co2 C19 . 2.0615(14) ?
    Co2 C21 . 2.0751(15) ?
    Co2 C20 . 2.0770(14) ?
    Co2 C18 . 2.1757(14) ?
    Co2 C22 . 2.1859(14) ?
    C18 C26 . 1.412(2) ?
    C18 C22 . 1.426(2) ?
    C18 C19 . 1.448(2) ?
    C19 C20 . 1.410(2) ?
    C19 H19 . 0.9500 ?
    C20 C21 . 1.417(2) ?
    C20 H20 . 0.9500 ?
    C21 C22 . 1.445(2) ?
    C21 H21 . 0.9500 ?
    C22 C23 . 1.416(2) ?
    C23 C24 . 1.365(2) ?
    C23 H23 . 0.9500 ?
    C24 C25 . 1.408(2) ?
    C24 H24 . 0.9500 ?
    C25 C26 . 1.365(2) ?
    C25 H25 . 0.9500 ?
    C26 H26 . 0.9500 ?
    C27 C28 . 1.394(2) ?
    C27 C34 . 1.515(2) ?
    C27 H27 . 0.945(19) ?
    C28 C29 . 1.502(2) ?
    C28 H28 . 0.93(2) ?
    C29 C30 . 1.513(3) ?
    C29 H29A . 0.9900 ?
    C29 H29B . 0.9900 ?
    C30 C31 . 1.517(2) ?
    C30 H30A . 0.9900 ?
    C30 H30B . 0.9900 ?
    C31 C32 . 1.387(2) ?
    C31 H31 . 0.934(18) ?
    C32 C33 . 1.514(2) ?
    C32 H32 . 0.957(18) ?
    C33 C34 . 1.521(3) ?
    C33 H33A . 0.9900 ?
    C33 H33B . 0.9900 ?
    C34 H34A . 0.9900 ?
    C34 H34B . 0.9900 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    C10 Co1 C14 . . 102.45(6) ?
    C10 Co1 C15 . . 84.96(6) ?
    C14 Co1 C15 . . 40.37(6) ?
    C10 Co1 C11 . . 40.58(6) ?
    C14 Co1 C11 . . 84.77(6) ?
    C15 Co1 C11 . . 94.50(6) ?
    C10 Co1 C2 . . 99.66(6) ?
    C14 Co1 C2 . . 148.83(6) ?
    C15 Co1 C2 . . 164.90(6) ?
    C11 Co1 C2 . . 98.33(6) ?
    C10 Co1 C4 . . 160.07(6) ?
    C14 Co1 C4 . . 95.81(6) ?
    C15 Co1 C4 . . 104.41(6) ?
    C11 Co1 C4 . . 151.42(6) ?
    C2 Co1 C4 . . 67.02(6) ?
    C10 Co1 C3 . . 135.52(6) ?
    C14 Co1 C3 . . 110.78(6) ?
    C15 Co1 C3 . . 139.25(6) ?
    C11 Co1 C3 . . 113.50(6) ?
    C2 Co1 C3 . . 39.71(6) ?
    C4 Co1 C3 . . 39.85(6) ?
    C10 Co1 C5 . . 122.26(6) ?
    C14 Co1 C5 . . 117.67(6) ?
    C15 Co1 C5 . . 99.41(6) ?
    C11 Co1 C5 . . 156.82(6) ?
    C2 Co1 C5 . . 65.92(6) ?
    C4 Co1 C5 . . 39.62(5) ?
    C3 Co1 C5 . . 65.95(6) ?
    C10 Co1 C1 . . 94.59(6) ?
    C14 Co1 C1 . . 155.71(6) ?
    C15 Co1 C1 . . 126.18(6) ?
    C11 Co1 C1 . . 119.14(6) ?
    C2 Co1 C1 . . 39.52(6) ?
    C4 Co1 C1 . . 65.62(5) ?
    C3 Co1 C1 . . 65.62(6) ?
    C5 Co1 C1 . . 38.10(5) ?
    C9 C1 C5 . . 119.64(14) ?
    C9 C1 C2 . . 132.58(14) ?
    C5 C1 C2 . . 107.74(13) ?
    C9 C1 Co1 . . 126.84(10) ?
    C5 C1 Co1 . . 70.90(8) ?
    C2 C1 Co1 . . 66.02(8) ?
    C3 C2 C1 . . 108.41(13) ?
    C3 C2 Co1 . . 70.72(8) ?
    C1 C2 Co1 . . 74.46(8) ?
    C3 C2 H2 . . 125.8 ?
    C1 C2 H2 . . 125.8 ?
    Co1 C2 H2 . . 120.7 ?
    C2 C3 C4 . . 107.94(13) ?
    C2 C3 Co1 . . 69.57(8) ?
    C4 C3 Co1 . . 69.63(8) ?
    C2 C3 H3 . . 126.0 ?
    C4 C3 H3 . . 126.0 ?
    Co1 C3 H3 . . 126.3 ?
    C3 C4 C5 . . 108.50(13) ?
    C3 C4 Co1 . . 70.52(8) ?
    C5 C4 Co1 . . 74.22(8) ?
    C3 C4 H4 . . 125.8 ?
    C5 C4 H4 . . 125.8 ?
    Co1 C4 H4 . . 121.2 ?
    C6 C5 C1 . . 119.93(13) ?
    C6 C5 C4 . . 132.96(14) ?
    C1 C5 C4 . . 107.04(13) ?
    C6 C5 Co1 . . 125.72(10) ?
    C1 C5 Co1 . . 71.00(8) ?
    C4 C5 Co1 . . 66.15(8) ?
    C7 C6 C5 . . 118.85(15) ?
    C7 C6 H6 . . 120.6 ?
    C5 C6 H6 . . 120.6 ?
    C6 C7 C8 . . 121.30(15) ?
    C6 C7 H7 . . 119.3 ?
    C8 C7 H7 . . 119.3 ?
    C9 C8 C7 . . 121.32(14) ?
    C9 C8 H8 . . 119.3 ?
    C7 C8 H8 . . 119.3 ?
    C8 C9 C1 . . 118.93(14) ?
    C8 C9 H9 . . 120.5 ?
    C1 C9 H9 . . 120.5 ?
    C11 C10 C17 . . 125.52(14) ?
    C11 C10 Co1 . . 70.45(8) ?
    C17 C10 Co1 . . 111.05(11) ?
    C11 C10 H10 . . 114.9(10) ?
    C17 C10 H10 . . 115.4(10) ?
    Co1 C10 H10 . . 108.4(10) ?
    C10 C11 C12 . . 122.84(14) ?
    C10 C11 Co1 . . 68.97(8) ?
    C12 C11 Co1 . . 113.28(11) ?
    C10 C11 H11 . . 117.5(10) ?
    C12 C11 H11 . . 116.0(10) ?
    Co1 C11 H11 . . 106.2(10) ?
    C11 C12 C13 . . 111.27(13) ?
    C11 C12 H12A . . 109.4 ?
    C13 C12 H12A . . 109.4 ?
    C11 C12 H12B . . 109.4 ?
    C13 C12 H12B . . 109.4 ?
    H12A C12 H12B . . 108.0 ?
    C14 C13 C12 . . 112.24(13) ?
    C14 C13 H13A . . 109.2 ?
    C12 C13 H13A . . 109.2 ?
    C14 C13 H13B . . 109.2 ?
    C12 C13 H13B . . 109.2 ?
    H13A C13 H13B . . 107.9 ?
    C15 C14 C13 . . 124.23(14) ?
    C15 C14 Co1 . . 69.95(8) ?
    C13 C14 Co1 . . 111.40(10) ?
    C15 C14 H14 . . 116.6(10) ?
    C13 C14 H14 . . 114.7(10) ?
    Co1 C14 H14 . . 109.3(10) ?
    C14 C15 C16 . . 123.58(15) ?
    C14 C15 Co1 . . 69.68(8) ?
    C16 C15 Co1 . . 112.73(10) ?
    C14 C15 H15 . . 118.6(10) ?
    C16 C15 H15 . . 113.5(10) ?
    Co1 C15 H15 . . 108.4(11) ?
    C15 C16 C17 . . 111.29(13) ?
    C15 C16 H16A . . 109.4 ?
    C17 C16 H16A . . 109.4 ?
    C15 C16 H16B . . 109.4 ?
    C17 C16 H16B . . 109.4 ?
    H16A C16 H16B . . 108.0 ?
    C10 C17 C16 . . 111.94(13) ?
    C10 C17 H17A . . 109.2 ?
    C16 C17 H17A . . 109.2 ?
    C10 C17 H17B . . 109.2 ?
    C16 C17 H17B . . 109.2 ?
    H17A C17 H17B . . 107.9 ?
    C28 Co2 C31 . . 85.13(7) ?
    C28 Co2 C32 . . 101.68(7) ?
    C31 Co2 C32 . . 40.20(7) ?
    C28 Co2 C27 . . 40.40(7) ?
    C31 Co2 C27 . . 95.39(7) ?
    C32 Co2 C27 . . 84.84(7) ?
    C28 Co2 C19 . . 100.47(7) ?
    C31 Co2 C19 . . 164.95(6) ?
    C32 Co2 C19 . . 148.37(7) ?
    C27 Co2 C19 . . 97.88(6) ?
    C28 Co2 C21 . . 160.50(7) ?
    C31 Co2 C21 . . 103.44(6) ?
    C32 Co2 C21 . . 95.93(6) ?
    C27 Co2 C21 . . 151.64(7) ?
    C19 Co2 C21 . . 67.16(6) ?
    C28 Co2 C20 . . 136.49(7) ?
    C31 Co2 C20 . . 138.07(7) ?
    C32 Co2 C20 . . 110.38(7) ?
    C27 Co2 C20 . . 113.49(7) ?
    C19 Co2 C20 . . 39.83(6) ?
    C21 Co2 C20 . . 39.90(6) ?
    C28 Co2 C18 . . 94.90(6) ?
    C31 Co2 C18 . . 126.28(6) ?
    C32 Co2 C18 . . 156.24(6) ?
    C27 Co2 C18 . . 118.53(6) ?
    C19 Co2 C18 . . 39.84(6) ?
    C21 Co2 C18 . . 65.84(6) ?
    C20 Co2 C18 . . 66.02(6) ?
    C28 Co2 C22 . . 122.44(7) ?
    C31 Co2 C22 . . 99.18(6) ?
    C32 Co2 C22 . . 118.15(6) ?
    C27 Co2 C22 . . 156.30(7) ?
    C19 Co2 C22 . . 65.99(6) ?
    C21 Co2 C22 . . 39.53(6) ?
    C20 Co2 C22 . . 65.93(6) ?
    C18 Co2 C22 . . 38.16(5) ?
    C26 C18 C22 . . 120.14(14) ?
    C26 C18 C19 . . 132.39(14) ?
    C22 C18 C19 . . 107.39(13) ?
    C26 C18 Co2 . . 125.78(10) ?
    C22 C18 Co2 . . 71.31(8) ?
    C19 C18 Co2 . . 65.83(8) ?
    C20 C19 C18 . . 108.45(13) ?
    C20 C19 Co2 . . 70.68(8) ?
    C18 C19 Co2 . . 74.34(8) ?
    C20 C19 H19 . . 125.8 ?
    C18 C19 H19 . . 125.8 ?
    Co2 C19 H19 . . 120.9 ?
    C19 C20 C21 . . 108.09(13) ?
    C19 C20 Co2 . . 69.49(8) ?
    C21 C20 Co2 . . 69.98(8) ?
    C19 C20 H20 . . 126.0 ?
    C21 C20 H20 . . 126.0 ?
    Co2 C20 H20 . . 126.1 ?
    C20 C21 C22 . . 108.44(14) ?
    C20 C21 Co2 . . 70.12(8) ?
    C22 C21 Co2 . . 74.37(8) ?
    C20 C21 H21 . . 125.8 ?
    C22 C21 H21 . . 125.8 ?
    Co2 C21 H21 . . 121.4 ?
    C23 C22 C18 . . 119.49(14) ?
    C23 C22 C21 . . 133.15(14) ?
    C18 C22 C21 . . 107.30(13) ?
    C23 C22 Co2 . . 126.47(10) ?
    C18 C22 Co2 . . 70.54(8) ?
    C21 C22 Co2 . . 66.10(8) ?
    C24 C23 C22 . . 118.78(15) ?
    C24 C23 H23 . . 120.6 ?
    C22 C23 H23 . . 120.6 ?
    C23 C24 C25 . . 121.56(15) ?
    C23 C24 H24 . . 119.2 ?
    C25 C24 H24 . . 119.2 ?
    C26 C25 C24 . . 121.30(15) ?
    C26 C25 H25 . . 119.3 ?
    C24 C25 H25 . . 119.3 ?
    C25 C26 C18 . . 118.71(15) ?
    C25 C26 H26 . . 120.6 ?
    C18 C26 H26 . . 120.6 ?
    C28 C27 C34 . . 122.49(15) ?
    C28 C27 Co2 . . 69.68(9) ?
    C34 C27 Co2 . . 113.45(11) ?
    C28 C27 H27 . . 115.8(12) ?
    C34 C27 H27 . . 117.2(12) ?
    Co2 C27 H27 . . 106.4(11) ?
    C27 C28 C29 . . 125.88(16) ?
    C27 C28 Co2 . . 69.92(9) ?
    C29 C28 Co2 . . 110.72(11) ?
    C27 C28 H28 . . 117.8(12) ?
    C29 C28 H28 . . 112.9(12) ?
    Co2 C28 H28 . . 108.5(12) ?
    C28 C29 C30 . . 112.79(14) ?
    C28 C29 H29A . . 109.0 ?
    C30 C29 H29A . . 109.0 ?
    C28 C29 H29B . . 109.0 ?
    C30 C29 H29B . . 109.0 ?
    H29A C29 H29B . . 107.8 ?
    C29 C30 C31 . . 111.63(13) ?
    C29 C30 H30A . . 109.3 ?
    C31 C30 H30A . . 109.3 ?
    C29 C30 H30B . . 109.3 ?
    C31 C30 H30B . . 109.3 ?
    H30A C30 H30B . . 108.0 ?
    C32 C31 C30 . . 122.65(15) ?
    C32 C31 Co2 . . 70.00(9) ?
    C30 C31 Co2 . . 112.77(11) ?
    C32 C31 H31 . . 117.5(11) ?
    C30 C31 H31 . . 116.2(11) ?
    Co2 C31 H31 . . 105.4(11) ?
    C31 C32 C33 . . 123.91(15) ?
    C31 C32 Co2 . . 69.80(9) ?
    C33 C32 Co2 . . 112.20(12) ?
    C31 C32 H32 . . 115.9(10) ?
    C33 C32 H32 . . 115.7(11) ?
    Co2 C32 H32 . . 108.1(11) ?
    C32 C33 C34 . . 112.29(14) ?
    C32 C33 H33A . . 109.1 ?
    C34 C33 H33A . . 109.1 ?
    C32 C33 H33B . . 109.1 ?
    C34 C33 H33B . . 109.1 ?
    H33A C33 H33B . . 107.9 ?
    C27 C34 C33 . . 112.45(13) ?
    C27 C34 H34A . . 109.1 ?
    C33 C34 H34A . . 109.1 ?
    C27 C34 H34B . . 109.1 ?
    C33 C34 H34B . . 109.1 ?
    H34A C34 H34B . . 107.8 ?
data_New_Global_Publ_Block
_journal_date_recd_electronic     2015-12-14
_journal_date_accepted     2016-01-06
_journal_name_full     'IUCrData'
_journal_year     2016
_journal_volume     1
_journal_issue      1
_journal_page_first     0
_journal_page_last     0
_journal_paper_category     HM
_journal_paper_doi     10.1107/S2414314616000274
_journal_coeditor_code     WM5256
_publ_contact_author_name     'Marko Hapke'
_publ_contact_author_address
;
Leibniz-Institut für Katalyse e.V. an der Universität Rostock,
Albert-Einstein-Strasse 29a, 18059 Rostock, Germany
;
_publ_contact_author_email     'marko.hapke@catalysis.de'
_publ_contact_author_fax     '+49 381 1281 51213'
_publ_contact_author_phone     '+49 381 1281 213'
_publ_section_title
;
Crystal structure of (η²,η²-cycloocta-1,5-diene)(η⁵-indenyl)cobalt(I)
;
loop_
    _publ_author_name
    _publ_author_footnote
    _publ_author_address
    'Jungk, Phillip' .
;
Leibniz-Institut für Katalyse e.V. an der Universität Rostock,
Albert-Einstein-Strasse 29a, 18059 Rostock,
Germany
;
    'Spannenberg, Anke' .
;
Leibniz-Institut für Katalyse e.V. an der Universität Rostock,
Albert-Einstein-Strasse 29a, 18059 Rostock,
Germany
;
    'Hapke, Marko' .
;
Leibniz-Institut für Katalyse e.V. an der Universität Rostock,
Albert-Einstein-Strasse 29a, 18059 Rostock,
Germany
;
_publ_section_synopsis
;
In[Co(C₈H₁₂)(C₉H₇)], the CoI atom is coordinated by the two double
bonds of the 1,5-cyclooctadiene ligand and η⁵-bonded to the indenyl ligand.
The asymmetric unit contains two molecules of the CoI complex with very
similar conformations. In the crystal, molecules are arranged into rows
parallel to [100].
;
