##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in          #
# Acta Crystallographica Section E. It conforms to the requirements of       #
# Notes for Authors for Acta Crystallographica Section E, and has been       #
# peer reviewed under the auspices of the IUCr Commission on Journals.       #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the journal # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_I
_audit_creation_method     SHELXL-2013
_database_code_depnum_ccdc_archive     'CCDC 979173'
_chemical_name_systematic
;
1,3,4-Tri-O-acetyl-2-N-(trifluoroacetyl)-β-L-fucose
;
_chemical_name_common     ?
_chemical_formula_moiety     'C14 H18 F3 N O8'
_chemical_formula_sum     'C14 H18 F3 N O8'
_chemical_formula_iupac     'C14 H18 F3 N O8'
_chemical_formula_weight     385.29
_chemical_melting_point_gt     430.5
_chemical_melting_point_lt     432.5
_symmetry_space_group_name_hall     'P 2ac 2ab'
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system     orthorhombic
_space_group_name_H-M_alt     'P 21 21 21'
_space_group_name_Hall     'P 2ac 2ab'
loop_
    _space_group_symop_operation_xyz
    'x, y, z'
    '-x+1/2, -y, z+1/2'
    '-x, y+1/2, -z+1/2'
    'x+1/2, -y+1/2, -z'
_cell_length_a     5.1818(10)
_cell_length_b     16.968(3)
_cell_length_c     19.484(4)
_cell_angle_alpha     90
_cell_angle_beta     90
_cell_angle_gamma     90
_cell_volume     1713.1(6)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     6913
_cell_measurement_theta_min     2.40
_cell_measurement_theta_max     30.54
_cell_measurement_temperature     100(2)
_cell_special_details     ?
_exptl_crystal_description     block
_exptl_crystal_colour     colourless
_exptl_crystal_size_max     0.480
_exptl_crystal_size_mid     0.310
_exptl_crystal_size_min     0.300
_exptl_crystal_density_diffrn     1.494
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     ?
_exptl_crystal_F_000     800
_exptl_absorpt_coefficient_mu     0.142
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(SADABS; Sheldrick, 2007)'
_shelx_estimated_absorpt_T_min     0.935
_shelx_estimated_absorpt_T_max     0.959
_exptl_absorpt_correction_T_min     0.839
_exptl_absorpt_correction_T_max     0.958
_exptl_special_details     ?
_diffrn_ambient_temperature     100(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker AXS Smart Apex CCD diffractometer'
_diffrn_measurement_method     'ω scans'
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     11394
_diffrn_reflns_av_R_equivalents     0.0291
_diffrn_reflns_theta_min     2.090
_diffrn_reflns_theta_max     28.280
_diffrn_reflns_theta_full     25.242
_diffrn_measured_fraction_theta_max     0.999
_diffrn_measured_fraction_theta_full     0.999
_diffrn_reflns_limit_h_min     -6
_diffrn_reflns_limit_h_max     6
_diffrn_reflns_limit_k_min     -22
_diffrn_reflns_limit_k_max     21
_diffrn_reflns_limit_l_min     -22
_diffrn_reflns_limit_l_max     25
_refine_special_details     ?
_reflns_number_total     4232
_reflns_number_gt     3869
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0418
_refine_ls_R_factor_gt     0.0373
_refine_ls_wR_factor_gt     0.0853
_refine_ls_wR_factor_ref     0.0878
_refine_ls_goodness_of_fit_ref     1.061
_refine_ls_restrained_S_all     1.061
_refine_ls_number_reflns     4232
_refine_ls_number_parameters     239
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
              'w=1/[σ²(Fo²)+(0.0424P)²+0.1715P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.000
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.298
_refine_diff_density_min     -0.170
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     .
_refine_ls_abs_structure_details
;
Flack parameter determined using 1493 quotients
[(I⁺)-(I⁻)]/[(I⁺)+(I⁻)]
(Parsons et al., 2013)
;
_refine_ls_abs_structure_Flack     0.4(3)
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'N' 'N' 0.0061 0.0033
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'F' 'F' 0.0171 0.0103
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'SMART (Bruker, 2002)'
_computing_cell_refinement     'SAINT-Plus (Bruker, 2003)'
_computing_data_reduction     'SAINT-Plus (Bruker, 2003)'
_computing_structure_solution     'SHELXS97 (Sheldrick, 2008)'
_computing_structure_refinement
;
SHELXL2013 (Sheldrick, 2008) and
SHELXLE (Hübschle et al., 2011)
;
_computing_molecular_graphics     'Mercury (Macrae et al., 2008)'
_computing_publication_material     'publCIF (Westrip, 2010)'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    C C1 0.3282(4) 0.43097(12) 0.65855(10) 0.0225(4) Uani d 1 . .
    H H1 0.1566 0.4327 0.6351 0.027 Uiso calc 1 . .
    C C2 0.3854(4) 0.50942(11) 0.69399(10) 0.0190(4) Uani d 1 . .
    H H2 0.5626 0.5077 0.7143 0.023 Uiso calc 1 . .
    C C3 0.1889(4) 0.52308(11) 0.75081(10) 0.0209(4) Uani d 1 . .
    H H3 0.0174 0.5351 0.7297 0.025 Uiso calc 1 . .
    C C4 0.1619(4) 0.45132(12) 0.79776(11) 0.0239(4) Uani d 1 . .
    H H4 0.0089 0.4585 0.8284 0.029 Uiso calc 1 . .
    C C5 0.1274(5) 0.37669(12) 0.75536(11) 0.0284(5) Uani d 1 . .
    H H5 -0.0392 0.3801 0.7296 0.034 Uiso calc 1 . .
    C C6 0.1278(6) 0.30211(14) 0.79839(12) 0.0417(7) Uani d 1 . .
    H H6A 0.1026 0.2563 0.7685 0.063 Uiso calc 1 . .
    H H6B -0.0124 0.3046 0.8321 0.063 Uiso calc 1 . .
    H H6C 0.2934 0.2973 0.8223 0.063 Uiso calc 1 . .
    C C7 0.4717(4) 0.36394(12) 0.55954(11) 0.0255(5) Uani d 1 . .
    C C8 0.6856(5) 0.35718(14) 0.50908(11) 0.0306(5) Uani d 1 . .
    H H8A 0.7102 0.3017 0.4968 0.046 Uiso calc 1 . .
    H H8B 0.8448 0.3779 0.5294 0.046 Uiso calc 1 . .
    H H8C 0.6427 0.3875 0.4678 0.046 Uiso calc 1 . .
    C C9 0.5799(4) 0.60760(12) 0.61779(10) 0.0201(4) Uani d 1 . .
    C C10 0.5121(4) 0.67368(12) 0.56627(11) 0.0231(4) Uani d 1 . .
    C C11 0.0942(5) 0.63360(13) 0.82140(11) 0.0274(5) Uani d 1 . .
    C C12 0.2160(6) 0.70111(14) 0.85856(13) 0.0361(6) Uani d 1 . .
    H H12A 0.0826 0.7392 0.8716 0.054 Uiso calc 1 . .
    H H12B 0.3424 0.7268 0.8285 0.054 Uiso calc 1 . .
    H H12C 0.3029 0.6816 0.8999 0.054 Uiso calc 1 . .
    C C13 0.3851(4) 0.47114(12) 0.90408(11) 0.0247(4) Uani d 1 . .
    C C14 0.6170(4) 0.44563(14) 0.94350(11) 0.0306(5) Uani d 1 . .
    H H14A 0.7671 0.4764 0.9287 0.046 Uiso calc 1 . .
    H H14B 0.6492 0.3895 0.9351 0.046 Uiso calc 1 . .
    H H14C 0.5873 0.4542 0.9926 0.046 Uiso calc 1 . .
    F F1 0.4052(3) 0.64366(8) 0.50988(6) 0.0343(3) Uani d 1 . .
    F F2 0.7207(3) 0.71321(8) 0.54797(7) 0.0374(3) Uani d 1 . .
    F F3 0.3429(3) 0.72485(8) 0.59280(7) 0.0373(4) Uani d 1 . .
    N N1 0.3700(3) 0.57409(10) 0.64480(8) 0.0203(4) Uani d 1 . .
    H H1A 0.2170 0.5916 0.6325 0.024 Uiso calc 1 . .
    O O1 0.3363(3) 0.36940(8) 0.70706(7) 0.0269(3) Uani d 1 . .
    O O2 0.5281(3) 0.41733(8) 0.61054(7) 0.0236(3) Uani d 1 . .
    O O3 0.2779(3) 0.59116(8) 0.78734(7) 0.0230(3) Uani d 1 . .
    O O4 0.3917(3) 0.44154(8) 0.83929(7) 0.0241(3) Uani d 1 . .
    O O5 0.2690(3) 0.32900(9) 0.55792(9) 0.0338(4) Uani d 1 . .
    O O6 0.8048(3) 0.59089(9) 0.62873(8) 0.0272(3) Uani d 1 . .
    O O7 -0.1313(3) 0.61666(11) 0.82064(9) 0.0382(4) Uani d 1 . .
    O O8 0.2109(3) 0.51128(9) 0.92552(8) 0.0292(4) Uani d 1 . .
_geom_special_details
;
All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    C1 O1 . 1.410(2) ?
    C1 O2 . 1.415(3) ?
    C1 C2 . 1.528(3) ?
    C1 H1 . 1.0000 ?
    C2 N1 . 1.459(2) ?
    C2 C3 . 1.522(3) ?
    C2 H2 . 1.0000 ?
    C3 O3 . 1.433(2) ?
    C3 C4 . 1.529(3) ?
    C3 H3 . 1.0000 ?
    C4 O4 . 1.449(3) ?
    C4 C5 . 1.523(3) ?
    C4 H4 . 1.0000 ?
    C5 O1 . 1.440(3) ?
    C5 C6 . 1.518(3) ?
    C5 H5 . 1.0000 ?
    C6 H6A . 0.9800 ?
    C6 H6B . 0.9800 ?
    C6 H6C . 0.9800 ?
    C7 O5 . 1.207(3) ?
    C7 O2 . 1.376(3) ?
    C7 C8 . 1.486(3) ?
    C8 H8A . 0.9800 ?
    C8 H8B . 0.9800 ?
    C8 H8C . 0.9800 ?
    C9 O6 . 1.218(3) ?
    C9 N1 . 1.335(3) ?
    C9 C10 . 1.545(3) ?
    C10 F2 . 1.321(2) ?
    C10 F1 . 1.332(2) ?
    C10 F3 . 1.338(2) ?
    C11 O7 . 1.203(3) ?
    C11 O3 . 1.366(3) ?
    C11 C12 . 1.495(3) ?
    C12 H12A . 0.9800 ?
    C12 H12B . 0.9800 ?
    C12 H12C . 0.9800 ?
    C13 O8 . 1.205(3) ?
    C13 O4 . 1.359(3) ?
    C13 C14 . 1.490(3) ?
    C14 H14A . 0.9800 ?
    C14 H14B . 0.9800 ?
    C14 H14C . 0.9800 ?
    N1 H1A . 0.8800 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O1 C1 O2 . . 107.48(16) ?
    O1 C1 C2 . . 109.69(16) ?
    O2 C1 C2 . . 107.42(17) ?
    O1 C1 H1 . . 110.7 ?
    O2 C1 H1 . . 110.7 ?
    C2 C1 H1 . . 110.7 ?
    N1 C2 C3 . . 109.07(16) ?
    N1 C2 C1 . . 110.34(15) ?
    C3 C2 C1 . . 109.37(16) ?
    N1 C2 H2 . . 109.3 ?
    C3 C2 H2 . . 109.3 ?
    C1 C2 H2 . . 109.3 ?
    O3 C3 C2 . . 105.59(16) ?
    O3 C3 C4 . . 111.98(16) ?
    C2 C3 C4 . . 112.03(17) ?
    O3 C3 H3 . . 109.0 ?
    C2 C3 H3 . . 109.0 ?
    C4 C3 H3 . . 109.0 ?
    O4 C4 C5 . . 107.73(17) ?
    O4 C4 C3 . . 110.49(17) ?
    C5 C4 C3 . . 110.39(16) ?
    O4 C4 H4 . . 109.4 ?
    C5 C4 H4 . . 109.4 ?
    C3 C4 H4 . . 109.4 ?
    O1 C5 C6 . . 106.8(2) ?
    O1 C5 C4 . . 109.73(17) ?
    C6 C5 C4 . . 113.17(18) ?
    O1 C5 H5 . . 109.0 ?
    C6 C5 H5 . . 109.0 ?
    C4 C5 H5 . . 109.0 ?
    C5 C6 H6A . . 109.5 ?
    C5 C6 H6B . . 109.5 ?
    H6A C6 H6B . . 109.5 ?
    C5 C6 H6C . . 109.5 ?
    H6A C6 H6C . . 109.5 ?
    H6B C6 H6C . . 109.5 ?
    O5 C7 O2 . . 121.8(2) ?
    O5 C7 C8 . . 126.4(2) ?
    O2 C7 C8 . . 111.75(19) ?
    C7 C8 H8A . . 109.5 ?
    C7 C8 H8B . . 109.5 ?
    H8A C8 H8B . . 109.5 ?
    C7 C8 H8C . . 109.5 ?
    H8A C8 H8C . . 109.5 ?
    H8B C8 H8C . . 109.5 ?
    O6 C9 N1 . . 127.7(2) ?
    O6 C9 C10 . . 120.00(18) ?
    N1 C9 C10 . . 112.33(17) ?
    F2 C10 F1 . . 108.16(17) ?
    F2 C10 F3 . . 108.13(16) ?
    F1 C10 F3 . . 107.12(18) ?
    F2 C10 C9 . . 110.97(18) ?
    F1 C10 C9 . . 110.66(16) ?
    F3 C10 C9 . . 111.64(17) ?
    O7 C11 O3 . . 123.0(2) ?
    O7 C11 C12 . . 126.8(2) ?
    O3 C11 C12 . . 110.2(2) ?
    C11 C12 H12A . . 109.5 ?
    C11 C12 H12B . . 109.5 ?
    H12A C12 H12B . . 109.5 ?
    C11 C12 H12C . . 109.5 ?
    H12A C12 H12C . . 109.5 ?
    H12B C12 H12C . . 109.5 ?
    O8 C13 O4 . . 123.3(2) ?
    O8 C13 C14 . . 126.1(2) ?
    O4 C13 C14 . . 110.56(19) ?
    C13 C14 H14A . . 109.5 ?
    C13 C14 H14B . . 109.5 ?
    H14A C14 H14B . . 109.5 ?
    C13 C14 H14C . . 109.5 ?
    H14A C14 H14C . . 109.5 ?
    H14B C14 H14C . . 109.5 ?
    C9 N1 C2 . . 122.31(17) ?
    C9 N1 H1A . . 118.8 ?
    C2 N1 H1A . . 118.8 ?
    C1 O1 C5 . . 110.62(16) ?
    C7 O2 C1 . . 115.46(16) ?
    C11 O3 C3 . . 116.22(17) ?
    C13 O4 C4 . . 117.13(17) ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    O1 C1 C2 N1 . . . . -178.28(17) ?
    O2 C1 C2 N1 . . . . 65.2(2) ?
    O1 C1 C2 C3 . . . . -58.3(2) ?
    O2 C1 C2 C3 . . . . -174.82(16) ?
    N1 C2 C3 O3 . . . . -67.37(19) ?
    C1 C2 C3 O3 . . . . 171.87(15) ?
    N1 C2 C3 C4 . . . . 170.49(16) ?
    C1 C2 C3 C4 . . . . 49.7(2) ?
    O3 C3 C4 O4 . . . . -48.1(2) ?
    C2 C3 C4 O4 . . . . 70.4(2) ?
    O3 C3 C4 C5 . . . . -167.13(18) ?
    C2 C3 C4 C5 . . . . -48.7(2) ?
    O4 C4 C5 O1 . . . . -65.9(2) ?
    C3 C4 C5 O1 . . . . 54.8(2) ?
    O4 C4 C5 C6 . . . . 53.2(3) ?
    C3 C4 C5 C6 . . . . 173.9(2) ?
    O6 C9 C10 F2 . . . . -10.1(3) ?
    N1 C9 C10 F2 . . . . 170.94(18) ?
    O6 C9 C10 F1 . . . . 110.0(2) ?
    N1 C9 C10 F1 . . . . -69.0(2) ?
    O6 C9 C10 F3 . . . . -130.8(2) ?
    N1 C9 C10 F3 . . . . 50.2(2) ?
    O6 C9 N1 C2 . . . . 0.2(3) ?
    C10 C9 N1 C2 . . . . 179.05(16) ?
    C3 C2 N1 C9 . . . . 137.83(19) ?
    C1 C2 N1 C9 . . . . -102.0(2) ?
    O2 C1 O1 C5 . . . . -176.42(15) ?
    C2 C1 O1 C5 . . . . 67.1(2) ?
    C6 C5 O1 C1 . . . . 171.70(18) ?
    C4 C5 O1 C1 . . . . -65.3(2) ?
    O5 C7 O2 C1 . . . . -2.9(3) ?
    C8 C7 O2 C1 . . . . 176.33(17) ?
    O1 C1 O2 C7 . . . . 81.6(2) ?
    C2 C1 O2 C7 . . . . -160.48(16) ?
    O7 C11 O3 C3 . . . . -1.2(3) ?
    C12 C11 O3 C3 . . . . 178.36(17) ?
    C2 C3 O3 C11 . . . . 154.73(16) ?
    C4 C3 O3 C11 . . . . -83.1(2) ?
    O8 C13 O4 C4 . . . . -7.8(3) ?
    C14 C13 O4 C4 . . . . 171.13(17) ?
    C5 C4 O4 C13 . . . . -142.17(18) ?
    C3 C4 O4 C13 . . . . 97.2(2) ?
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    N1 H1A O6 1_455 0.88 2.137 2.959(2) 155.2
    C3 H3 O6 1_455 1.00 2.445 3.308(3) 144.1
    C6 H6B F3 3_546 0.98 2.628 3.487(3) 146.5
    C8 H8A O5 4_556 0.98 2.479 3.445(3) 168.7
    C8 H8B O5 1_655 0.98 2.414 3.206(3) 137.4
    C8 H8C O8 2_564 0.98 2.643 3.443(3) 138.9
    C14 H14A O8 1_655 0.98 2.375 3.292(3) 155.3
_shelxl_version_number         .2013
data_global
_journal_date_recd_electronic     2013-12-06
_journal_date_accepted     2013-12-30
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2014
_journal_volume     70
_journal_issue      2
_journal_page_first     o134
_journal_page_last     o135
_journal_paper_category     QO
_journal_paper_doi     10.1107/S1600536813034958
_journal_coeditor_code     BV2229
_publ_contact_author
; Peter  Norris
  Department of Chemistry
  Youngstown State University
  1 University Plaza
  Youngstown, OH 44555-3663
  USA
;
_publ_contact_author_name     'Peter Norris'
_publ_contact_author_address
;
Department of Chemistry
Youngstown State University
1 University Plaza
Youngstown, OH 44555-3663
USA
;
_publ_contact_author_email     'pnorris@ysu.edu'
_publ_contact_author_fax     '(330)941-1579'
_publ_contact_author_phone     '(330)941-1553'
_publ_section_title
;
1,3,4-Tri-O-acetyl-2-N-(trifluoroacetyl)-β-L-fucose
;
_publ_section_title_footnote     .
loop_
    _publ_author_name
    _publ_author_footnote
    _publ_author_address
    'McCutcheon, David C.' .
;
Department of Chemistry
Youngstown State University
1 University Plaza
Youngstown, OH 44555-3663
USA
;
    'Norris, Peter' .
;
Department of Chemistry
Youngstown State University
1 University Plaza
Youngstown, OH 44555-3663
USA
;
    'Zeller, Matthias' .
;
Department of Chemistry
Youngstown State University
1 University Plaza
Youngstown, OH 44555-3663
USA
;
