##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in          #
# Acta Crystallographica Section E. It conforms to the requirements of       #
# Notes for Authors for Acta Crystallographica Section E, and has been       #
# peer reviewed under the auspices of the IUCr Commission on Journals.       #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the journal # 
# article from which it was obtained.                                        #
#                                                                            #
##############################################################################
data_global
_audit_creation_method     'PLATON <TABLE ACC> option'
_journal_date_recd_electronic     2012-03-23
_journal_date_accepted     2012-03-24
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2012
_journal_volume     68
_journal_issue      5
_journal_page_first     m590
_journal_page_last     m591
_journal_paper_category     QM
_journal_paper_doi     10.1107/S1600536812012998
_journal_coeditor_code     SJ5223
_publ_contact_author_name
; Dr. Mehmet Akkurt
;
_publ_contact_author_address
;
Department of Physics
Faculty of Sciences
Erciyes University
38039 Kayseri
Turkey
;
_publ_contact_author_email     akkurt@erciyes.edu.tr
_publ_contact_author_fax     '+90-352-4374933'
_publ_contact_author_phone     '+90-352-4374901 ext. 33106'
_publ_section_title
;
Chlorido[1-phenyl-3-(2,3,5,6-tetramethylbenzyl)benzimidazol-2-ylidene]silver(I)
;
loop_
    _publ_author_name
    _publ_author_address
    'Mehmet Akkurt'
; Department of Physics,
  Faculty of Sciences,
  Erciyes University,
  38039 Kayseri,
  Turkey
;
    'Senem Akkoç'
; Department of Chemistry,
  Faculty of Sciences,
  Erciyes University,
  38039 Kayseri,
  Turkey
;
    'Yetkin Gök'
;
  Department of Chemistry,
  Faculty of Arts and Sciences,
  Ínönü University,
  44280 Malatya,
  Turkey
;
    'Yılmaz Dağdemir'
; Department of Physics,
  Faculty of Sciences,
  Erciyes University,
  38039 Kayseri,
  Turkey
;
    'Muhammad Nawaz Tahir'
;
Department of Physics,
University of Sargodha,
Sargodha,
Pakistan
;
data_I
_chemical_name_systematic
;
Chlorido[1-phenyl-3-(2,3,5,6-tetramethylbenzyl)benzimidazol-2-ylidene]silver(I)
;
_chemical_name_common     ?
_chemical_formula_moiety     'C24 H24 Ag Cl N2'
_chemical_formula_sum     'C24 H24 Ag Cl N2'
_chemical_formula_structural     ?
_chemical_formula_iupac     '[Ag Cl (C24 H24 N2)]'
_chemical_formula_weight     483.77
_chemical_melting_point     ?
_symmetry_cell_setting     monoclinic
_symmetry_space_group_name_H-M     'P 21/n'
_symmetry_space_group_name_Hall     '-P 2yn'
loop_
    _symmetry_equiv_pos_site_id
    _symmetry_equiv_pos_as_xyz
    1 x,y,z
    2 1/2-x,1/2+y,1/2-z
    3 -x,-y,-z
    4 1/2+x,1/2-y,1/2+z
_cell_length_a     9.1439(2)
_cell_length_b     18.7633(4)
_cell_length_c     13.2710(3)
_cell_angle_alpha     90
_cell_angle_beta     109.8990(10)
_cell_angle_gamma     90
_cell_volume     2140.96(8)
_cell_formula_units_Z     4
_cell_measurement_reflns_used     3354
_cell_measurement_theta_min     2.38
_cell_measurement_theta_max     28.30
_cell_measurement_temperature     296(2)
_cell_special_details
;
;
_exptl_crystal_description     prism
_exptl_crystal_colour     white
_exptl_crystal_size_max     0.35
_exptl_crystal_size_mid     0.22
_exptl_crystal_size_min     0.20
_exptl_crystal_size_rad     ?
_exptl_crystal_density_diffrn     1.501
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'Not Measured'
_exptl_crystal_F_000     984
_exptl_absorpt_coefficient_mu     1.078
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(SADABS; Bruker, 2005)'
_exptl_absorpt_correction_T_min     0.752
_exptl_absorpt_correction_T_max     0.806
_exptl_special_details
;
M.p.: 524--525 K. n(CN)=1593.31
cm^-1. 1^H NMR (DMSO) δ: 2.11, 2.18 (s, 12H,
NCH₂C₆H(CH₃)₄-2,3,5,6); 5.61 (s, 2H,
NCH₂C₆H(CH₃)₄-2,3,5,6); 6.66--7.87 (m, 10H, Ar-H). ¹³C
NMR (DMSO) d: 16.4, 20.8 (NCH₂C₆H(CH₃)₄-2,3,5,6); 55.2
(NCH₂C₆H(CH₃)₄-2,3,5,6); 112.5, 112.8, 124.9, 125.4, 126.8,
129.8, 130.4, 131.3, 132.7, 133.9, 134.6, 138.9 (Ar-C); the carbene
carbon was not detected. Analysis calculated for C₂₄H₂₄N₂AgCl: C 59.58,
H 5.00, N 5.79%. Found: C 59.56, H 5.01, N 5.78%.
;
_diffrn_ambient_temperature     296(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker Kappa APEXII CCD'
_diffrn_measurement_method     ω
_diffrn_detector_area_resol_mean     8.00
_diffrn_reflns_number     19846
_diffrn_reflns_av_R_equivalents     0.0403
_diffrn_reflns_av_sigmaI/netI     0.0520
_diffrn_reflns_theta_min     2.38
_diffrn_reflns_theta_max     28.30
_diffrn_reflns_theta_full     28.30
_diffrn_measured_fraction_theta_max     0.994
_diffrn_measured_fraction_theta_full     0.994
_diffrn_reflns_limit_h_min     -10
_diffrn_reflns_limit_h_max     12
_diffrn_reflns_limit_k_min     -25
_diffrn_reflns_limit_k_max     16
_diffrn_reflns_limit_l_min     -17
_diffrn_reflns_limit_l_max     17
_diffrn_reflns_reduction_process
;
;
_refine_special_details
;
Refinement on F² for ALL reflections except those flagged by the user
for potential systematic errors. Weighted R-factors wR and all
goodnesses of fit S are based on F², conventional
R-factors R are based on F, with F set to zero for
negative F². The observed criterion of F² > σ(F²)
is used only for calculating -R-factor-obs etc. and is not
relevant to the choice of reflections for refinement. R-factors based
on F² are statistically about twice as large as those based on
F, and R-factors based on ALL data will be even larger.
;
_reflns_number_total     5288
_reflns_number_gt     3354
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0764
_refine_ls_R_factor_gt     0.0362
_refine_ls_wR_factor_gt     0.0675
_refine_ls_wR_factor_ref     0.0798
_refine_ls_goodness_of_fit_ref     1.009
_refine_ls_restrained_S_all     1.009
_refine_ls_number_reflns     5288
_refine_ls_number_parameters     257
_refine_ls_number_restraints     0
_refine_ls_number_constraints     ?
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
         'calc w=1/[σ²(Fo²)+(0.0308P)²+0.1600P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.000
_refine_diff_density_max     0.380
_refine_diff_density_min     -0.376
_refine_ls_extinction_method     'none'
_refine_ls_abs_structure_details     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    C C 0.0033 0.0016 ' International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    H H 0.0000 0.0000 ' International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    Ag Ag -0.8971 1.1015
                        ' International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    Cl Cl 0.1484 0.1585 ' International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    N N 0.0061 0.0033 ' International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'APEX2 (Bruker, 2009)'
_computing_cell_refinement     'SAINT (Bruker, 2009)'
_computing_data_reduction     'SAINT (Bruker, 2009)'
_computing_structure_solution     'SHELXS97 (Sheldrick, 2008)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 2008)'
_computing_molecular_graphics
                  'ORTEP-3 for Windows (Farrugia, 1997) and PLATON (Spek, 2009)'
_computing_publication_material
                                'WinGX (Farrugia, 1999) and PLATON (Spek, 2009)'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_thermal_displace_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Ag Ag1 0.25184(3) 0.849530(10)
                                 0.17444(2) 0.04760(10)
                                                      Uani d . 1.000 . .
    Cl Cl1 0.43000(9) 0.77142(4) 0.14398(7) 0.0572(3) Uani d . 1.000 . .
    N N1 -0.0611(3) 0.92849(11) 0.11403(17) 0.0370(7) Uani d . 1.000 . .
    N N2 0.1099(3) 0.98412(11) 0.24355(18) 0.0419(8) Uani d . 1.000 . .
    C C1 -0.1317(3) 0.99141(14) 0.1290(2) 0.0383(9) Uani d . 1.000 . .
    C C2 -0.2743(3) 1.02215(16) 0.0728(3) 0.0516(11) Uani d . 1.000 . .
    C C3 -0.3022(4) 1.08812(18) 0.1066(3) 0.0633(14) Uani d . 1.000 . .
    C C4 -0.1939(4) 1.12282(17) 0.1930(3) 0.0600(13) Uani d . 1.000 . .
    C C5 -0.0523(4) 1.09315(15) 0.2480(2) 0.0490(11) Uani d . 1.000 . .
    C C6 -0.0233(3) 1.02675(14) 0.2127(2) 0.0400(9) Uani d . 1.000 . .
    C C7 0.0885(3) 0.92485(14) 0.1829(2) 0.0407(9) Uani d . 1.000 . .
    C C8 -0.1372(3) 0.87529(14) 0.0361(2) 0.0365(8) Uani d . 1.000 . .
    C C9 -0.0741(4) 0.85480(15) -0.0403(2) 0.0458(10) Uani d . 1.000 . .
    C C10 -0.1480(4) 0.80302(16) -0.1139(2) 0.0552(11) Uani d . 1.000 . .
    C C11 -0.2846(4) 0.77302(16) -0.1119(2) 0.0552(11) Uani d . 1.000 . .
    C C12 -0.3471(4) 0.79363(16) -0.0351(3) 0.0536(11) Uani d . 1.000 . .
    C C13 -0.2733(3) 0.84494(14) 0.0388(2) 0.0443(10) Uani d . 1.000 . .
    C C14 0.2555(4) 1.00783(17) 0.3248(2) 0.0575(11) Uani d . 1.000 . .
    C C15 0.3702(3) 0.95064(15) 0.3774(2) 0.0452(10) Uani d . 1.000 . .
    C C16 0.3525(4) 0.91300(16) 0.4642(2) 0.0480(10) Uani d . 1.000 . .
    C C17 0.4668(4) 0.86531(16) 0.5207(2) 0.0579(11) Uani d . 1.000 . .
    C C18 0.5916(4) 0.85445(17) 0.4869(3) 0.0675(12) Uani d . 1.000 . .
    C C19 0.6107(4) 0.8891(2) 0.4013(3) 0.0639(11) Uani d . 1.000 . .
    C C20 0.4998(4) 0.93808(17) 0.3455(2) 0.0556(11) Uani d . 1.000 . .
    C C21 0.2094(4) 0.9235(2) 0.4940(3) 0.0758(14) Uani d . 1.000 . .
    C C22 0.4607(5) 0.8255(2) 0.6185(3) 0.0917(18) Uani d . 1.000 . .
    C C23 0.7508(5) 0.8708(3) 0.3695(4) 0.115(2) Uani d . 1.000 . .
    C C24 0.5189(5) 0.9767(2) 0.2499(3) 0.0853(17) Uani d . 1.000 . .
    H H2 -0.34700 0.99920 0.01520 0.0620 Uiso c R 1.000 . .
    H H3 -0.39630 1.11050 0.07090 0.0760 Uiso c R 1.000 . .
    H H4 -0.21850 1.16730 0.21380 0.0720 Uiso c R 1.000 . .
    H H5 0.02020 1.11610 0.30560 0.0590 Uiso c R 1.000 . .
    H H9 0.01720 0.87570 -0.04210 0.0550 Uiso c R 1.000 . .
    H H10 -0.10550 0.78830 -0.16490 0.0660 Uiso c R 1.000 . .
    H H11 -0.33500 0.73880 -0.16250 0.0660 Uiso c R 1.000 . .
    H H12 -0.43850 0.77290 -0.03330 0.0640 Uiso c R 1.000 . .
    H H13 -0.31510 0.85920 0.09040 0.0530 Uiso c R 1.000 . .
    H H14A 0.22980 1.03330 0.38010 0.0690 Uiso c R 1.000 . .
    H H14B 0.30560 1.04140 0.29150 0.0690 Uiso c R 1.000 . .
    H H18 0.66720 0.82180 0.52420 0.0810 Uiso c R 1.000 . .
    H H21A 0.22080 0.96590 0.53640 0.1140 Uiso c R 1.000 . .
    H H21B 0.19590 0.88320 0.53450 0.1140 Uiso c R 1.000 . .
    H H21C 0.12030 0.92820 0.43010 0.1140 Uiso c R 1.000 . .
    H H22A 0.37210 0.79440 0.59830 0.1370 Uiso c R 1.000 . .
    H H22B 0.45230 0.85900 0.67090 0.1370 Uiso c R 1.000 . .
    H H22C 0.55390 0.79790 0.64840 0.1370 Uiso c R 1.000 . .
    H H23A 0.71950 0.83940 0.30890 0.1730 Uiso c R 1.000 . .
    H H23B 0.82820 0.84780 0.42840 0.1730 Uiso c R 1.000 . .
    H H23C 0.79320 0.91370 0.35120 0.1730 Uiso c R 1.000 . .
    H H24A 0.59720 1.01290 0.27490 0.1280 Uiso c R 1.000 . .
    H H24B 0.42190 0.99840 0.20850 0.1280 Uiso c R 1.000 . .
    H H24C 0.54970 0.94330 0.20620 0.1280 Uiso c R 1.000 . .
_geom_special_details
;
Bond distances, angles etc. have been calculated using the rounded
fractional coordinates. All su's are estimated from the variances of the
(full) variance-covariance matrix. The cell e.s.d.'s are taken into account in
the estimation of distances, angles and torsion angles
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_1
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Ag1 Cl1 . . 2.3267(9) no
    Ag1 C7 . . 2.087(3) no
    N1 C1 . . 1.392(4) no
    N1 C7 . . 1.364(4) no
    N1 C8 . . 1.435(3) no
    N2 C6 . . 1.397(4) no
    N2 C7 . . 1.348(3) no
    N2 C14 . . 1.468(4) no
    C1 C2 . . 1.388(4) no
    C1 C6 . . 1.381(4) no
    C2 C3 . . 1.370(5) no
    C3 C4 . . 1.395(5) no
    C4 C5 . . 1.370(5) no
    C5 C6 . . 1.388(4) no
    C8 C9 . . 1.381(4) no
    C8 C13 . . 1.380(4) no
    C9 C10 . . 1.380(4) no
    C10 C11 . . 1.379(5) no
    C11 C12 . . 1.383(5) no
    C12 C13 . . 1.376(4) no
    C14 C15 . . 1.497(4) no
    C15 C16 . . 1.407(4) no
    C15 C20 . . 1.407(5) no
    C16 C17 . . 1.386(4) no
    C16 C21 . . 1.503(5) no
    C17 C18 . . 1.376(5) no
    C17 C22 . . 1.515(5) no
    C18 C19 . . 1.371(5) no
    C19 C20 . . 1.382(5) no
    C19 C23 . . 1.518(6) no
    C20 C24 . . 1.522(5) no
    C2 H2 . . 0.9300 no
    C3 H3 . . 0.9300 no
    C4 H4 . . 0.9300 no
    C5 H5 . . 0.9300 no
    C9 H9 . . 0.9300 no
    C10 H10 . . 0.9300 no
    C11 H11 . . 0.9300 no
    C12 H12 . . 0.9300 no
    C13 H13 . . 0.9300 no
    C14 H14A . . 0.9700 no
    C14 H14B . . 0.9700 no
    C18 H18 . . 0.9300 no
    C21 H21A . . 0.9600 no
    C21 H21B . . 0.9600 no
    C21 H21C . . 0.9600 no
    C22 H22A . . 0.9600 no
    C22 H22B . . 0.9600 no
    C22 H22C . . 0.9600 no
    C23 H23A . . 0.9600 no
    C23 H23B . . 0.9600 no
    C23 H23C . . 0.9600 no
    C24 H24A . . 0.9600 no
    C24 H24B . . 0.9600 no
    C24 H24C . . 0.9600 no
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_2
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    Cl1 Ag1 C7 . . . 172.84(7) no
    C1 N1 C7 . . . 110.8(2) no
    C1 N1 C8 . . . 123.9(2) no
    C7 N1 C8 . . . 125.3(2) no
    C6 N2 C7 . . . 111.3(2) no
    C6 N2 C14 . . . 121.6(2) no
    C7 N2 C14 . . . 126.9(3) no
    N1 C1 C2 . . . 132.2(3) no
    N1 C1 C6 . . . 106.3(2) no
    C2 C1 C6 . . . 121.2(3) no
    C1 C2 C3 . . . 116.4(3) no
    C2 C3 C4 . . . 122.1(3) no
    C3 C4 C5 . . . 121.8(3) no
    C4 C5 C6 . . . 116.1(3) no
    N2 C6 C1 . . . 106.0(2) no
    N2 C6 C5 . . . 131.5(3) no
    C1 C6 C5 . . . 122.4(3) no
    Ag1 C7 N1 . . . 124.81(18) no
    Ag1 C7 N2 . . . 129.1(2) no
    N1 C7 N2 . . . 105.5(2) no
    N1 C8 C9 . . . 120.1(3) no
    N1 C8 C13 . . . 119.2(2) no
    C9 C8 C13 . . . 120.7(3) no
    C8 C9 C10 . . . 119.3(3) no
    C9 C10 C11 . . . 120.2(3) no
    C10 C11 C12 . . . 120.3(3) no
    C11 C12 C13 . . . 119.7(3) no
    C8 C13 C12 . . . 119.9(3) no
    N2 C14 C15 . . . 116.2(2) no
    C14 C15 C16 . . . 119.0(3) no
    C14 C15 C20 . . . 120.5(3) no
    C16 C15 C20 . . . 120.4(3) no
    C15 C16 C17 . . . 119.4(3) no
    C15 C16 C21 . . . 120.2(3) no
    C17 C16 C21 . . . 120.4(3) no
    C16 C17 C18 . . . 118.4(3) no
    C16 C17 C22 . . . 122.7(3) no
    C18 C17 C22 . . . 118.9(3) no
    C17 C18 C19 . . . 123.6(3) no
    C18 C19 C20 . . . 118.8(3) no
    C18 C19 C23 . . . 118.7(4) no
    C20 C19 C23 . . . 122.4(4) no
    C15 C20 C19 . . . 119.3(3) no
    C15 C20 C24 . . . 121.2(3) no
    C19 C20 C24 . . . 119.5(3) no
    C1 C2 H2 . . . 122.00 no
    C3 C2 H2 . . . 122.00 no
    C2 C3 H3 . . . 119.00 no
    C4 C3 H3 . . . 119.00 no
    C3 C4 H4 . . . 119.00 no
    C5 C4 H4 . . . 119.00 no
    C4 C5 H5 . . . 122.00 no
    C6 C5 H5 . . . 122.00 no
    C8 C9 H9 . . . 120.00 no
    C10 C9 H9 . . . 120.00 no
    C9 C10 H10 . . . 120.00 no
    C11 C10 H10 . . . 120.00 no
    C10 C11 H11 . . . 120.00 no
    C12 C11 H11 . . . 120.00 no
    C11 C12 H12 . . . 120.00 no
    C13 C12 H12 . . . 120.00 no
    C8 C13 H13 . . . 120.00 no
    C12 C13 H13 . . . 120.00 no
    N2 C14 H14A . . . 108.00 no
    N2 C14 H14B . . . 108.00 no
    C15 C14 H14A . . . 108.00 no
    C15 C14 H14B . . . 108.00 no
    H14A C14 H14B . . . 107.00 no
    C17 C18 H18 . . . 118.00 no
    C19 C18 H18 . . . 118.00 no
    C16 C21 H21A . . . 109.00 no
    C16 C21 H21B . . . 109.00 no
    C16 C21 H21C . . . 109.00 no
    H21A C21 H21B . . . 110.00 no
    H21A C21 H21C . . . 109.00 no
    H21B C21 H21C . . . 110.00 no
    C17 C22 H22A . . . 110.00 no
    C17 C22 H22B . . . 109.00 no
    C17 C22 H22C . . . 109.00 no
    H22A C22 H22B . . . 109.00 no
    H22A C22 H22C . . . 109.00 no
    H22B C22 H22C . . . 109.00 no
    C19 C23 H23A . . . 109.00 no
    C19 C23 H23B . . . 109.00 no
    C19 C23 H23C . . . 109.00 no
    H23A C23 H23B . . . 109.00 no
    H23A C23 H23C . . . 110.00 no
    H23B C23 H23C . . . 109.00 no
    C20 C24 H24A . . . 109.00 no
    C20 C24 H24B . . . 109.00 no
    C20 C24 H24C . . . 109.00 no
    H24A C24 H24B . . . 109.00 no
    H24A C24 H24C . . . 109.00 no
    H24B C24 H24C . . . 110.00 no
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C7 N1 C1 C2 . . . . 172.8(3) no
    C8 N1 C1 C2 . . . . -7.1(5) no
    C7 N1 C1 C6 . . . . -2.1(3) no
    C8 N1 C1 C6 . . . . 178.0(2) no
    C1 N1 C7 Ag1 . . . . -169.48(19) no
    C8 N1 C7 Ag1 . . . . 10.4(4) no
    C1 N1 C7 N2 . . . . 2.2(3) no
    C8 N1 C7 N2 . . . . -178.0(2) no
    C7 N1 C8 C13 . . . . 122.9(3) no
    C1 N1 C8 C9 . . . . 123.0(3) no
    C7 N1 C8 C9 . . . . -56.9(4) no
    C1 N1 C8 C13 . . . . -57.2(4) no
    C7 N2 C14 C15 . . . . -26.7(4) no
    C6 N2 C7 N1 . . . . -1.4(3) no
    C14 N2 C7 N1 . . . . -175.3(3) no
    C6 N2 C14 C15 . . . . 160.1(3) no
    C14 N2 C6 C1 . . . . 174.4(2) no
    C7 N2 C6 C5 . . . . -176.4(3) no
    C14 N2 C6 C5 . . . . -2.2(5) no
    C6 N2 C7 Ag1 . . . . 169.7(2) no
    C14 N2 C7 Ag1 . . . . -4.1(4) no
    C7 N2 C6 C1 . . . . 0.2(3) no
    N1 C1 C2 C3 . . . . -175.7(3) no
    N1 C1 C6 C5 . . . . 178.1(3) no
    C6 C1 C2 C3 . . . . -1.5(5) no
    C2 C1 C6 C5 . . . . 2.5(4) no
    C2 C1 C6 N2 . . . . -174.4(3) no
    N1 C1 C6 N2 . . . . 1.1(3) no
    C1 C2 C3 C4 . . . . -0.2(5) no
    C2 C3 C4 C5 . . . . 1.0(6) no
    C3 C4 C5 C6 . . . . 0.0(5) no
    C4 C5 C6 N2 . . . . 174.4(3) no
    C4 C5 C6 C1 . . . . -1.7(4) no
    N1 C8 C9 C10 . . . . 179.3(2) no
    C9 C8 C13 C12 . . . . 0.1(4) no
    C13 C8 C9 C10 . . . . -0.5(4) no
    N1 C8 C13 C12 . . . . -179.7(3) no
    C8 C9 C10 C11 . . . . 1.0(4) no
    C9 C10 C11 C12 . . . . -1.1(5) no
    C10 C11 C12 C13 . . . . 0.8(5) no
    C11 C12 C13 C8 . . . . -0.3(4) no
    N2 C14 C15 C16 . . . . -83.2(3) no
    N2 C14 C15 C20 . . . . 101.2(3) no
    C14 C15 C16 C17 . . . . -173.2(3) no
    C14 C15 C16 C21 . . . . 7.9(4) no
    C20 C15 C16 C17 . . . . 2.4(4) no
    C20 C15 C16 C21 . . . . -176.5(3) no
    C14 C15 C20 C19 . . . . 174.6(3) no
    C14 C15 C20 C24 . . . . -6.2(4) no
    C16 C15 C20 C19 . . . . -0.9(4) no
    C16 C15 C20 C24 . . . . 178.3(3) no
    C15 C16 C17 C18 . . . . -2.5(4) no
    C15 C16 C17 C22 . . . . 176.8(3) no
    C21 C16 C17 C18 . . . . 176.4(3) no
    C21 C16 C17 C22 . . . . -4.3(5) no
    C16 C17 C18 C19 . . . . 1.1(5) no
    C22 C17 C18 C19 . . . . -178.2(3) no
    C17 C18 C19 C20 . . . . 0.4(5) no
    C17 C18 C19 C23 . . . . -178.0(4) no
    C18 C19 C20 C15 . . . . -0.5(5) no
    C18 C19 C20 C24 . . . . -179.7(3) no
    C23 C19 C20 C15 . . . . 177.9(3) no
    C23 C19 C20 C24 . . . . -1.3(5) no
loop_
    _geom_hbond_atom_site_label_D
    _geom_hbond_atom_site_label_H
    _geom_hbond_atom_site_label_A
    _geom_hbond_site_symmetry_A
    _geom_hbond_distance_DH
    _geom_hbond_distance_HA
    _geom_hbond_distance_DA
    _geom_hbond_angle_DHA
    _geom_hbond_publ_flag
    C9 H9 Cg2 3_575 0.93 2.69 3.507(4) 147 yes
    C22 H22A Cg3 4_565 0.96 2.80 3.525(4) 133 yes
