##############################################################################
#                                                                            #
# This CIF contains the data in a paper accepted for publication in          #
# Acta Crystallographica Section E. It conforms to the requirements of       #
# Notes for Authors for Acta Crystallographica Section E, and has been       #
# peer reviewed under the auspices of the IUCr Commission on Journals.       #
#                                                                            #
# Full details of the Crystallographic Information File format               #
# are given in the paper "The Crystallographic Information File (CIF):       #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H.      #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685].                  #
#                                                                            #
# The current version of the core CIF dictionary is obtainable from          #
# ftp://ftp.iucr.org/pub/cif_core.dic.                                       #
#                                                                            #
# Software is freely available for graphical display of the structure(s)     #
# in this CIF. For information consult the CIF software page                 #
# http://www.iucr.org/resources/cif/software.                                #
#                                                                            #
# This file may be used for bona fide research purposes within the           #
# scientific community so long as proper attribution is given to the journal # 
# article from which it was obtained.                                        #
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##############################################################################
data_global
_audit_creation_method     SHELXL-97
_journal_date_recd_electronic     2011-04-20
_journal_date_accepted     2011-04-26
_journal_name_full     'Acta Crystallographica, Section E'
_journal_year     2011
_journal_volume     67
_journal_issue      6
_journal_page_first     m660
_journal_page_last     m660
_journal_paper_category     QM
_journal_coeditor_code     BT5525
_publ_contact_author
;
     Dr. Seik Weng Ng
     Department of Chemistry
     University of Malaya
     50603 Kuala Lumpur
     Malaysia
;
_publ_contact_author_email     seikweng@um.edu.my
_publ_contact_author_fax     '03 7967 4193'
_publ_contact_author_phone     '03 7967 6778'
_publ_section_title
;
Tetrachloridobis(dibenzyl sulfoxide-κO)tin(IV)
;
loop_
    _publ_author_name
    _publ_author_address
    'Keng, Thy Chun'
;
     Department of Chemistry
     University of Malaya
     50603 Kuala Lumpur
     Malaysia
;
    'Lo, Kong Mun'
;
     Department of Chemistry
     University of Malaya
     50603 Kuala Lumpur
     Malaysia
;
    'Ng, Seik Weng'
;
     Department of Chemistry
     University of Malaya
     50603 Kuala Lumpur
     Malaysia
;
data_I
_audit_creation_method     SHELXL-97
_chemical_name_systematic
;
Tetrachloridobis(dibenzyl sulfoxide-κO)tin(IV)
;
_chemical_name_common     ?
_chemical_formula_moiety     'C28 H28 Cl4 O2 S2 Sn'
_chemical_formula_sum     'C28 H28 Cl4 O2 S2 Sn'
_chemical_formula_iupac     '[Sn Cl4 (C14 H14 O S)2]'
_chemical_formula_weight     721.11
_chemical_melting_point     ?
_symmetry_cell_setting     triclinic
_symmetry_space_group_name_H-M     'P -1'
_symmetry_space_group_name_Hall     '-P 1'
loop_
    _symmetry_equiv_pos_as_xyz
    'x, y, z'
    '-x, -y, -z'
_cell_length_a     10.79820(10)
_cell_length_b     11.14690(10)
_cell_length_c     14.9456(2)
_cell_angle_alpha     80.8623(6)
_cell_angle_beta     87.8310(5)
_cell_angle_gamma     61.4279(6)
_cell_volume     1558.31(3)
_cell_formula_units_Z     2
_cell_measurement_reflns_used     9933
_cell_measurement_theta_min     2.33
_cell_measurement_theta_max     28.32
_cell_measurement_temperature     100(2)
_exptl_crystal_description     Cuboic
_exptl_crystal_colour     Colorless
_exptl_crystal_size_max     0.30
_exptl_crystal_size_mid     0.30
_exptl_crystal_size_min     0.30
_exptl_crystal_density_diffrn     1.537
_exptl_crystal_density_meas     ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000     724
_exptl_absorpt_coefficient_mu     1.321
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details     '(SADABS; Sheldrick, 1996)'
_exptl_absorpt_correction_T_min     0.6927
_exptl_absorpt_correction_T_max     0.6927
_diffrn_ambient_temperature     100(2)
_diffrn_radiation_type     MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_source     'fine-focus sealed tube'
_diffrn_radiation_monochromator     graphite
_diffrn_measurement_device_type     'Bruker SMART APEX'
_diffrn_measurement_method     ω
_diffrn_detector_area_resol_mean     ?
_diffrn_reflns_number     14537
_diffrn_reflns_av_R_equivalents     0.0186
_diffrn_reflns_av_sigmaI/netI     0.0263
_diffrn_reflns_theta_min     1.38
_diffrn_reflns_theta_max     27.50
_diffrn_reflns_theta_full     27.50
_diffrn_measured_fraction_theta_max     0.997
_diffrn_measured_fraction_theta_full     0.997
_diffrn_reflns_limit_h_min     -14
_diffrn_reflns_limit_h_max     14
_diffrn_reflns_limit_k_min     -14
_diffrn_reflns_limit_k_max     14
_diffrn_reflns_limit_l_min     -19
_diffrn_reflns_limit_l_max     19
_diffrn_standards_number     0
_diffrn_standards_interval_count     0
_diffrn_standards_interval_time     0
_diffrn_standards_decay_%     0
_reflns_number_total     7139
_reflns_number_gt     6609
_reflns_threshold_expression     I>2σ(I)
_refine_ls_structure_factor_coef     Fsqd
_refine_ls_matrix_type     full
_refine_ls_R_factor_all     0.0309
_refine_ls_R_factor_gt     0.0276
_refine_ls_wR_factor_gt     0.0707
_refine_ls_wR_factor_ref     0.0732
_refine_ls_goodness_of_fit_ref     1.049
_refine_ls_restrained_S_all     1.049
_refine_ls_number_reflns     7139
_refine_ls_number_parameters     334
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment     constr
_refine_ls_weighting_scheme     calc
_refine_ls_weighting_details
         'calc w=1/[σ²(Fo²)+(0.0353P)²+1.7363P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary     difmap
_refine_ls_shift/su_max     0.001
_refine_ls_shift/su_mean     0.001
_refine_diff_density_max     0.829
_refine_diff_density_min     -1.024
_refine_ls_extinction_method     none
_refine_ls_extinction_coef     ?
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
    'C' 'C' 0.0033 0.0016
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'H' 'H' 0.0000 0.0000
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'O' 'O' 0.0106 0.0060
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'S' 'S' 0.1246 0.1234
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Cl' 'Cl' 0.1484 0.1585
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
    'Sn' 'Sn' -0.6537 1.4246
                         'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection     'APEX2 (Bruker, 2009)'
_computing_cell_refinement     'SAINT (Bruker, 2009)'
_computing_data_reduction     'SAINT (Bruker, 2009)'
_computing_structure_solution     'SHELXS97 (Sheldrick, 2008)'
_computing_structure_refinement     'SHELXL97 (Sheldrick, 2008)'
_computing_molecular_graphics     'X-SEED (Barbour, 2001)'
_computing_publication_material     'publCIF (Westrip, 2010)'
loop_
    _atom_site_type_symbol
    _atom_site_label
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_occupancy
    _atom_site_symmetry_multiplicity
    _atom_site_disorder_assembly
    _atom_site_disorder_group
    Sn Sn1 0.596648(15) 0.444875(15) 0.252840(10) 0.01653(5) Uani d . 1 1 . .
    Cl Cl1 0.38718(6) 0.50368(6) 0.34078(4) 0.02255(12) Uani d . 1 1 . .
    Cl Cl2 0.73128(6) 0.23980(6) 0.35805(4) 0.02240(12) Uani d . 1 1 . .
    Cl Cl3 0.79172(6) 0.41742(6) 0.16256(4) 0.02173(11) Uani d . 1 1 . .
    Cl Cl4 0.51422(7) 0.34402(7) 0.15481(4) 0.02784(13) Uani d . 1 1 . .
    S S1 0.46614(6) 0.65868(6) 0.06715(4) 0.01692(11) Uani d . 1 1 . .
    S S2 0.63003(5) 0.55337(5) 0.43151(4) 0.01626(11) Uani d . 1 1 . .
    O O1 0.47446(16) 0.64050(16) 0.17213(10) 0.0186(3) Uani d . 1 1 . .
    O O2 0.63931(16) 0.56674(16) 0.32657(10) 0.0180(3) Uani d . 1 1 . .
    C C1 0.4837(2) 0.8131(2) 0.03527(16) 0.0220(5) Uani d . 1 1 . .
    H H1A 0.4505 0.8534 -0.0287 0.026 Uiso calc R 1 1 . .
    H H1B 0.4254 0.8828 0.0739 0.026 Uiso calc R 1 1 . .
    C C2 0.6361(2) 0.7760(2) 0.04695(17) 0.0230(5) Uani d . 1 1 . .
    C C3 0.7306(3) 0.7160(3) -0.01962(17) 0.0261(5) Uani d . 1 1 . .
    H H3 0.6970 0.7040 -0.0736 0.031 Uiso calc R 1 1 . .
    C C4 0.8721(3) 0.6743(3) -0.0072(2) 0.0336(6) Uani d . 1 1 . .
    H H4 0.9359 0.6332 -0.0524 0.040 Uiso calc R 1 1 . .
    C C5 0.9213(3) 0.6923(3) 0.0710(2) 0.0390(7) Uani d . 1 1 . .
    H H5 1.0188 0.6634 0.0795 0.047 Uiso calc R 1 1 . .
    C C6 0.8287(3) 0.7522(3) 0.1369(2) 0.0375(6) Uani d . 1 1 . .
    H H6 0.8627 0.7655 0.1903 0.045 Uiso calc R 1 1 . .
    C C7 0.6863(3) 0.7931(3) 0.12542(19) 0.0294(5) Uani d . 1 1 . .
    H H7 0.6232 0.8328 0.1713 0.035 Uiso calc R 1 1 . .
    C C8 0.2791(2) 0.7253(3) 0.04071(16) 0.0219(5) Uani d . 1 1 . .
    H H8A 0.2587 0.7669 -0.0242 0.026 Uiso calc R 1 1 . .
    H H8B 0.2580 0.6471 0.0502 0.026 Uiso calc R 1 1 . .
    C C9 0.1836(2) 0.8315(2) 0.09659(16) 0.0211(5) Uani d . 1 1 . .
    C C10 0.1443(2) 0.7906(3) 0.18065(17) 0.0250(5) Uani d . 1 1 . .
    H H10 0.1788 0.6949 0.2027 0.030 Uiso calc R 1 1 . .
    C C11 0.0553(3) 0.8881(3) 0.23263(18) 0.0307(6) Uani d . 1 1 . .
    H H11 0.0295 0.8589 0.2902 0.037 Uiso calc R 1 1 . .
    C C12 0.0036(3) 1.0280(3) 0.2011(2) 0.0334(6) Uani d . 1 1 . .
    H H12 -0.0575 1.0948 0.2367 0.040 Uiso calc R 1 1 . .
    C C13 0.0418(3) 1.0697(3) 0.1173(2) 0.0305(6) Uani d . 1 1 . .
    H H13 0.0064 1.1655 0.0954 0.037 Uiso calc R 1 1 . .
    C C14 0.1313(3) 0.9726(3) 0.06500(18) 0.0258(5) Uani d . 1 1 . .
    H H14 0.1572 1.0022 0.0076 0.031 Uiso calc R 1 1 . .
    C C15 0.7840(2) 0.5654(2) 0.46182(16) 0.0207(4) Uani d . 1 1 . .
    H H15A 0.7877 0.6433 0.4219 0.025 Uiso calc R 1 1 . .
    H H15B 0.7804 0.5812 0.5254 0.025 Uiso calc R 1 1 . .
    C C16 0.9120(2) 0.4305(3) 0.45052(17) 0.0224(5) Uani d . 1 1 . .
    C C17 0.9583(3) 0.3185(3) 0.52021(19) 0.0289(5) Uani d . 1 1 . .
    H H17 0.9121 0.3281 0.5760 0.035 Uiso calc R 1 1 . .
    C C18 1.0721(3) 0.1923(3) 0.5085(2) 0.0358(6) Uani d . 1 1 . .
    H H18 1.1032 0.1156 0.5562 0.043 Uiso calc R 1 1 . .
    C C19 1.1403(3) 0.1780(3) 0.4276(2) 0.0377(7) Uani d . 1 1 . .
    H H19 1.2188 0.0918 0.4200 0.045 Uiso calc R 1 1 . .
    C C20 1.0945(3) 0.2887(3) 0.3583(2) 0.0397(7) Uani d . 1 1 . .
    H H20 1.1411 0.2786 0.3026 0.048 Uiso calc R 1 1 . .
    C C21 0.9800(3) 0.4155(3) 0.36924(18) 0.0302(6) Uani d . 1 1 . .
    H H21 0.9485 0.4916 0.3211 0.036 Uiso calc R 1 1 . .
    C C22 0.4876(2) 0.7197(2) 0.45106(16) 0.0209(4) Uani d . 1 1 . .
    H H22A 0.3974 0.7174 0.4483 0.025 Uiso calc R 1 1 . .
    H H22B 0.5011 0.7332 0.5132 0.025 Uiso calc R 1 1 . .
    C C23 0.4757(2) 0.8415(2) 0.38565(16) 0.0190(4) Uani d . 1 1 . .
    C C24 0.3880(2) 0.8883(2) 0.30771(16) 0.0227(5) Uani d . 1 1 . .
    H H24 0.3403 0.8397 0.2948 0.027 Uiso calc R 1 1 . .
    C C25 0.3701(3) 1.0057(3) 0.24878(18) 0.0310(6) Uani d . 1 1 . .
    H H25 0.3087 1.0385 0.1964 0.037 Uiso calc R 1 1 . .
    C C26 0.4414(3) 1.0743(3) 0.2664(2) 0.0361(6) Uani d . 1 1 . .
    H H26 0.4290 1.1543 0.2258 0.043 Uiso calc R 1 1 . .
    C C27 0.5305(3) 1.0283(3) 0.3421(2) 0.0373(7) Uani d . 1 1 . .
    H H27 0.5805 1.0756 0.3531 0.045 Uiso calc R 1 1 . .
    C C28 0.5472(3) 0.9122(3) 0.40263(19) 0.0281(5) Uani d . 1 1 . .
    H H28 0.6073 0.8812 0.4555 0.034 Uiso calc R 1 1 . .
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_site_symmetry_2
    _geom_bond_distance
    _geom_bond_publ_flag
    Sn1 O2 . 2.0938(16) ?
    Sn1 O1 . 2.1176(16) ?
    Sn1 Cl3 . 2.3772(5) ?
    Sn1 Cl2 . 2.3800(6) ?
    Sn1 Cl4 . 2.4045(6) ?
    Sn1 Cl1 . 2.4297(5) ?
    S1 O1 . 1.5502(16) ?
    S1 C1 . 1.809(2) ?
    S1 C8 . 1.822(2) ?
    S2 O2 . 1.5558(16) ?
    S2 C15 . 1.810(2) ?
    S2 C22 . 1.816(2) ?
    C1 C2 . 1.503(3) ?
    C1 H1A . 0.9900 ?
    C1 H1B . 0.9900 ?
    C2 C7 . 1.387(4) ?
    C2 C3 . 1.400(3) ?
    C3 C4 . 1.379(4) ?
    C3 H3 . 0.9500 ?
    C4 C5 . 1.383(4) ?
    C4 H4 . 0.9500 ?
    C5 C6 . 1.383(4) ?
    C5 H5 . 0.9500 ?
    C6 C7 . 1.388(4) ?
    C6 H6 . 0.9500 ?
    C7 H7 . 0.9500 ?
    C8 C9 . 1.498(3) ?
    C8 H8A . 0.9900 ?
    C8 H8B . 0.9900 ?
    C9 C10 . 1.389(3) ?
    C9 C14 . 1.397(3) ?
    C10 C11 . 1.386(4) ?
    C10 H10 . 0.9500 ?
    C11 C12 . 1.386(4) ?
    C11 H11 . 0.9500 ?
    C12 C13 . 1.383(4) ?
    C12 H12 . 0.9500 ?
    C13 C14 . 1.389(4) ?
    C13 H13 . 0.9500 ?
    C14 H14 . 0.9500 ?
    C15 C16 . 1.508(3) ?
    C15 H15A . 0.9900 ?
    C15 H15B . 0.9900 ?
    C16 C21 . 1.386(4) ?
    C16 C17 . 1.387(4) ?
    C17 C18 . 1.388(4) ?
    C17 H17 . 0.9500 ?
    C18 C19 . 1.382(4) ?
    C18 H18 . 0.9500 ?
    C19 C20 . 1.375(5) ?
    C19 H19 . 0.9500 ?
    C20 C21 . 1.393(4) ?
    C20 H20 . 0.9500 ?
    C21 H21 . 0.9500 ?
    C22 C23 . 1.495(3) ?
    C22 H22A . 0.9900 ?
    C22 H22B . 0.9900 ?
    C23 C28 . 1.393(3) ?
    C23 C24 . 1.394(3) ?
    C24 C25 . 1.390(4) ?
    C24 H24 . 0.9500 ?
    C25 C26 . 1.374(4) ?
    C25 H25 . 0.9500 ?
    C26 C27 . 1.377(5) ?
    C26 H26 . 0.9500 ?
    C27 C28 . 1.394(4) ?
    C27 H27 . 0.9500 ?
    C28 H28 . 0.9500 ?
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle
    _geom_angle_publ_flag
    O2 Sn1 O1 . . 81.00(6) ?
    O2 Sn1 Cl3 . . 88.98(4) ?
    O1 Sn1 Cl3 . . 88.48(4) ?
    O2 Sn1 Cl2 . . 92.70(4) ?
    O1 Sn1 Cl2 . . 173.13(4) ?
    Cl3 Sn1 Cl2 . . 94.17(2) ?
    O2 Sn1 Cl4 . . 169.67(5) ?
    O1 Sn1 Cl4 . . 88.95(4) ?
    Cl3 Sn1 Cl4 . . 93.16(2) ?
    Cl2 Sn1 Cl4 . . 97.22(2) ?
    O2 Sn1 Cl1 . . 86.64(4) ?
    O1 Sn1 Cl1 . . 85.29(4) ?
    Cl3 Sn1 Cl1 . . 172.87(2) ?
    Cl2 Sn1 Cl1 . . 91.656(19) ?
    Cl4 Sn1 Cl1 . . 90.18(2) ?
    O1 S1 C1 . . 101.73(10) ?
    O1 S1 C8 . . 103.26(10) ?
    C1 S1 C8 . . 101.23(11) ?
    O2 S2 C15 . . 100.62(10) ?
    O2 S2 C22 . . 104.75(10) ?
    C15 S2 C22 . . 101.73(11) ?
    S1 O1 Sn1 . . 121.84(9) ?
    S2 O2 Sn1 . . 121.81(9) ?
    C2 C1 S1 . . 108.98(16) ?
    C2 C1 H1A . . 109.9 ?
    S1 C1 H1A . . 109.9 ?
    C2 C1 H1B . . 109.9 ?
    S1 C1 H1B . . 109.9 ?
    H1A C1 H1B . . 108.3 ?
    C7 C2 C3 . . 119.4(2) ?
    C7 C2 C1 . . 120.7(2) ?
    C3 C2 C1 . . 119.8(2) ?
    C4 C3 C2 . . 120.3(2) ?
    C4 C3 H3 . . 119.9 ?
    C2 C3 H3 . . 119.9 ?
    C3 C4 C5 . . 120.0(3) ?
    C3 C4 H4 . . 120.0 ?
    C5 C4 H4 . . 120.0 ?
    C4 C5 C6 . . 120.2(3) ?
    C4 C5 H5 . . 119.9 ?
    C6 C5 H5 . . 119.9 ?
    C5 C6 C7 . . 120.2(3) ?
    C5 C6 H6 . . 119.9 ?
    C7 C6 H6 . . 119.9 ?
    C6 C7 C2 . . 120.0(3) ?
    C6 C7 H7 . . 120.0 ?
    C2 C7 H7 . . 120.0 ?
    C9 C8 S1 . . 113.76(16) ?
    C9 C8 H8A . . 108.8 ?
    S1 C8 H8A . . 108.8 ?
    C9 C8 H8B . . 108.8 ?
    S1 C8 H8B . . 108.8 ?
    H8A C8 H8B . . 107.7 ?
    C10 C9 C14 . . 118.9(2) ?
    C10 C9 C8 . . 120.2(2) ?
    C14 C9 C8 . . 120.9(2) ?
    C11 C10 C9 . . 120.6(2) ?
    C11 C10 H10 . . 119.7 ?
    C9 C10 H10 . . 119.7 ?
    C10 C11 C12 . . 120.3(2) ?
    C10 C11 H11 . . 119.8 ?
    C12 C11 H11 . . 119.8 ?
    C13 C12 C11 . . 119.5(3) ?
    C13 C12 H12 . . 120.3 ?
    C11 C12 H12 . . 120.3 ?
    C12 C13 C14 . . 120.5(3) ?
    C12 C13 H13 . . 119.7 ?
    C14 C13 H13 . . 119.7 ?
    C13 C14 C9 . . 120.2(2) ?
    C13 C14 H14 . . 119.9 ?
    C9 C14 H14 . . 119.9 ?
    C16 C15 S2 . . 107.39(16) ?
    C16 C15 H15A . . 110.2 ?
    S2 C15 H15A . . 110.2 ?
    C16 C15 H15B . . 110.2 ?
    S2 C15 H15B . . 110.2 ?
    H15A C15 H15B . . 108.5 ?
    C21 C16 C17 . . 119.5(2) ?
    C21 C16 C15 . . 120.5(2) ?
    C17 C16 C15 . . 119.9(2) ?
    C16 C17 C18 . . 120.1(3) ?
    C16 C17 H17 . . 119.9 ?
    C18 C17 H17 . . 119.9 ?
    C19 C18 C17 . . 120.2(3) ?
    C19 C18 H18 . . 119.9 ?
    C17 C18 H18 . . 119.9 ?
    C20 C19 C18 . . 119.9(3) ?
    C20 C19 H19 . . 120.1 ?
    C18 C19 H19 . . 120.1 ?
    C19 C20 C21 . . 120.3(3) ?
    C19 C20 H20 . . 119.8 ?
    C21 C20 H20 . . 119.8 ?
    C16 C21 C20 . . 119.9(3) ?
    C16 C21 H21 . . 120.0 ?
    C20 C21 H21 . . 120.0 ?
    C23 C22 S2 . . 114.98(16) ?
    C23 C22 H22A . . 108.5 ?
    S2 C22 H22A . . 108.5 ?
    C23 C22 H22B . . 108.5 ?
    S2 C22 H22B . . 108.5 ?
    H22A C22 H22B . . 107.5 ?
    C28 C23 C24 . . 119.2(2) ?
    C28 C23 C22 . . 121.2(2) ?
    C24 C23 C22 . . 119.6(2) ?
    C25 C24 C23 . . 120.2(2) ?
    C25 C24 H24 . . 119.9 ?
    C23 C24 H24 . . 119.9 ?
    C26 C25 C24 . . 119.9(3) ?
    C26 C25 H25 . . 120.1 ?
    C24 C25 H25 . . 120.1 ?
    C25 C26 C27 . . 120.8(3) ?
    C25 C26 H26 . . 119.6 ?
    C27 C26 H26 . . 119.6 ?
    C26 C27 C28 . . 119.8(3) ?
    C26 C27 H27 . . 120.1 ?
    C28 C27 H27 . . 120.1 ?
    C23 C28 C27 . . 120.0(2) ?
    C23 C28 H28 . . 120.0 ?
    C27 C28 H28 . . 120.0 ?
loop_
    _geom_torsion_atom_site_label_1
    _geom_torsion_atom_site_label_2
    _geom_torsion_atom_site_label_3
    _geom_torsion_atom_site_label_4
    _geom_torsion_site_symmetry_1
    _geom_torsion_site_symmetry_2
    _geom_torsion_site_symmetry_3
    _geom_torsion_site_symmetry_4
    _geom_torsion
    _geom_torsion_publ_flag
    C1 S1 O1 Sn1 . . . . -136.20(11) ?
    C8 S1 O1 Sn1 . . . . 119.12(11) ?
    O2 Sn1 O1 S1 . . . . 140.81(11) ?
    Cl3 Sn1 O1 S1 . . . . 51.60(10) ?
    Cl4 Sn1 O1 S1 . . . . -41.59(10) ?
    Cl1 Sn1 O1 S1 . . . . -131.86(10) ?
    C15 S2 O2 Sn1 . . . . 138.94(11) ?
    C22 S2 O2 Sn1 . . . . -115.80(11) ?
    O1 Sn1 O2 S2 . . . . 132.52(11) ?
    Cl3 Sn1 O2 S2 . . . . -138.85(10) ?
    Cl2 Sn1 O2 S2 . . . . -44.73(10) ?
    Cl4 Sn1 O2 S2 . . . . 119.0(2) ?
    Cl1 Sn1 O2 S2 . . . . 46.77(10) ?
    O1 S1 C1 C2 . . . . 77.36(18) ?
    C8 S1 C1 C2 . . . . -176.37(17) ?
    S1 C1 C2 C7 . . . . -96.3(2) ?
    S1 C1 C2 C3 . . . . 80.0(2) ?
    C7 C2 C3 C4 . . . . 0.1(4) ?
    C1 C2 C3 C4 . . . . -176.3(2) ?
    C2 C3 C4 C5 . . . . -0.3(4) ?
    C3 C4 C5 C6 . . . . -0.1(4) ?
    C4 C5 C6 C7 . . . . 0.8(5) ?
    C5 C6 C7 C2 . . . . -1.1(4) ?
    C3 C2 C7 C6 . . . . 0.6(4) ?
    C1 C2 C7 C6 . . . . 177.0(2) ?
    O1 S1 C8 C9 . . . . 41.3(2) ?
    C1 S1 C8 C9 . . . . -63.7(2) ?
    S1 C8 C9 C10 . . . . -86.7(2) ?
    S1 C8 C9 C14 . . . . 94.0(2) ?
    C14 C9 C10 C11 . . . . -0.3(4) ?
    C8 C9 C10 C11 . . . . -179.6(2) ?
    C9 C10 C11 C12 . . . . 0.3(4) ?
    C10 C11 C12 C13 . . . . -0.1(4) ?
    C11 C12 C13 C14 . . . . -0.2(4) ?
    C12 C13 C14 C9 . . . . 0.2(4) ?
    C10 C9 C14 C13 . . . . 0.1(4) ?
    C8 C9 C14 C13 . . . . 179.4(2) ?
    O2 S2 C15 C16 . . . . -73.55(17) ?
    C22 S2 C15 C16 . . . . 178.78(16) ?
    S2 C15 C16 C21 . . . . 92.2(2) ?
    S2 C15 C16 C17 . . . . -84.7(2) ?
    C21 C16 C17 C18 . . . . 0.1(4) ?
    C15 C16 C17 C18 . . . . 177.0(2) ?
    C16 C17 C18 C19 . . . . 0.4(4) ?
    C17 C18 C19 C20 . . . . -0.6(4) ?
    C18 C19 C20 C21 . . . . 0.3(5) ?
    C17 C16 C21 C20 . . . . -0.4(4) ?
    C15 C16 C21 C20 . . . . -177.3(2) ?
    C19 C20 C21 C16 . . . . 0.2(4) ?
    O2 S2 C22 C23 . . . . -35.0(2) ?
    C15 S2 C22 C23 . . . . 69.5(2) ?
    S2 C22 C23 C28 . . . . -90.2(2) ?
    S2 C22 C23 C24 . . . . 92.0(2) ?
    C28 C23 C24 C25 . . . . -1.3(4) ?
    C22 C23 C24 C25 . . . . 176.6(2) ?
    C23 C24 C25 C26 . . . . 1.4(4) ?
    C24 C25 C26 C27 . . . . -0.2(4) ?
    C25 C26 C27 C28 . . . . -1.1(4) ?
    C24 C23 C28 C27 . . . . 0.1(4) ?
    C22 C23 C28 C27 . . . . -177.8(2) ?
    C26 C27 C28 C23 . . . . 1.1(4) ?
