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Kinetics of the reaction of diphenyl chlorophosphate with the 4-nitrophenolate ion under inverse phase transfer catalysis conditions

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Theoretical and Experimental Chemistry Aims and scope

The reaction of diphenyl chlorophosphate with the 4-nitrophenolate ion was studied in the presence of a series of para derivatives of pyridine 1-oxide under inverse phase transfer catalysis (IPTC) conditions. The reaction proceeds due to the formation of an ionic intermediate in the organic phase, namely, 1-(diphenoxyphosphoryl) oxypyridinium salts. This conclusion was indicated by both 1H NMR and IR spectroscopy.

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Authors and Affiliations

  1. L. M. Litvinenko Institute of Physical Organic Chemistry and Coal Chemistry, Vul. R. Luxemburg, 70, Donets’k, 83114, Ukraine

    V. N. Anishchenko, V. I. Rybachenko, K. Yu. Chotii & A. N. Red’ko

Authors
  1. V. N. Anishchenko
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  2. V. I. Rybachenko
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  3. K. Yu. Chotii
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  4. A. N. Red’ko
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Corresponding author

Correspondence to V. N. Anishchenko.

Additional information

Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 48, No. 3, pp. 159-162, May-June, 2012.

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Anishchenko, V.N., Rybachenko, V.I., Chotii, K.Y. et al. Kinetics of the reaction of diphenyl chlorophosphate with the 4-nitrophenolate ion under inverse phase transfer catalysis conditions. Theor Exp Chem 48, 172–175 (2012). https://doi.org/10.1007/s11237-012-9257-7

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  • DOI: https://doi.org/10.1007/s11237-012-9257-7

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