Three faces of the second law. I. Master equation formulation

Massimiliano Esposito and Christian Van den Broeck
Phys. Rev. E 82, 011143 – Published 30 July 2010

Abstract

We propose a formulation of stochastic thermodynamics for systems subjected to nonequilibrium constraints (i.e. broken detailed balance at steady state) and furthermore driven by external time-dependent forces. A splitting of the second law occurs in this description leading to three second-law-like relations. The general results are illustrated on specific solvable models. The present paper uses a master equation based approach.

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  • Received 10 May 2010

DOI:https://doi.org/10.1103/PhysRevE.82.011143

©2010 American Physical Society

Authors & Affiliations

Massimiliano Esposito

  • Center for Nonlinear Phenomena and Complex Systems, Université Libre de Bruxelles, CP 231, Campus Plaine, B-1050 Brussels, Belgium

Christian Van den Broeck

  • Faculty of Sciences, Hasselt University, B-3590 Diepenbeek, Belgium

See Also

Three faces of the second law. II. Fokker-Planck formulation

Christian Van den Broeck and Massimiliano Esposito
Phys. Rev. E 82, 011144 (2010)

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Vol. 82, Iss. 1 — July 2010

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